Total synthesis of (+)-isolaurepinnacin. Use of acetal-alkene cyclizations to prepare highly functionalized seven-membered cyclic ethers

Journal of the American Chemical Society

Volumn 119, Issue 10, 1997, Pages 2446-2452

  Berger, Daniel ^a,b   Overman, Larry E ^a   Renhowe, Paul A ^a,c  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b PFIZER INC   (United States)

^c NOVARTIS PHARMA AG   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ISOLAUREPINNACIN; OXEPANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHIRALITY; DRUG SYNTHESIS; ENANTIOMER; IN VITRO STUDY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030899135     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja964080b     Document Type: Article

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55. 13C NMR spectrum: δ 63.3 (natural), 63.1 (epi), 61.7 (epi), 61.4 (natural).