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2+ were available in high purity from previous work.
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22
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1842267934
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Paper in preparation
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•- radical anion, electrochemically generated from the dppz ligand in a thin layer electrode cell, proved impossible due to strong sample luminescence: Waterland, M. R.; Gordon, K. C.; McGarvey, J. J.; Jayaweera, P. M. Paper in preparation.
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1842385477
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note
-
The enhancement patterns observed in the ground state RR spectra at each probe wavelength in the presence and absence of DNA suggest a lowering of intensity coupled with a red shift of the dppz component of the MLCT absorption upon intercalation, represented schematically here: [equation presented]
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24
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1842319881
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Coates, C. Ph.D. Thesis, QUB, 1996; to be published.
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25
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1842280663
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There are minor differences between the spectra of 1 and 2. Closer inspection reveals weak features attributable to phen or bpy, respectively, suggesting a small degree of overlap in this spectral region between the dppz intraligand absorption and the MLCT transitions to bpy/phen ligands.
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