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Volumn 119, Issue 26, 1997, Pages 6115-6125

Oxygen transfer from organoelement oxides to carbon monoxide catalyzed by transition metal carbonyls

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CARBONYL DERIVATIVE; OXIDE;

EID: 0030803440     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja970158s     Document Type: Article
Times cited : (16)

References (53)
  • 18
    • 16944365507 scopus 로고    scopus 로고
    • To be submitted for publication
    • 2Cl, which is known to be present in small concentration (Rosini, G. P.; Goldman, A. S. To be submitted for publication). However, since any such pathway is quite minor, this possibility was not pursued further.
    • Rosini, G.P.1    Goldman, A.S.2
  • 20
    • 16944367101 scopus 로고    scopus 로고
    • Personal communication, to be submitted for publication
    • Nolan, S. P. Personal communication, to be submitted for publication.
    • Nolan, S.P.1
  • 21
    • 0040862714 scopus 로고
    • D. Van Nostrand Co.: Princeton, NJ
    • The solubility of CO in dichloroethane is estimated to be approximately 7.4 mM under 800 Torr of CO, based on values for benzene (7.4 mM, 298°), chlorobenzene (6.4 mM, 293°), and chloroform (8.4 mM, 298°): (a) Linke, W. F. In Solubilities of Inorganic and Metal Organic Compounds, 4th ed.; D. Van Nostrand Co.: Princeton, NJ, 1958; Vol. 1, p 453. (b) Gerrard, W. Solubility of Gases and Liquids; Plenum Press: New York, 1976; p 141.
    • (1958) Solubilities of Inorganic and Metal Organic Compounds, 4th Ed. , vol.1 , pp. 453
    • Linke, W.F.1
  • 22
    • 0003819098 scopus 로고
    • Plenum Press: New York
    • The solubility of CO in dichloroethane is estimated to be approximately 7.4 mM under 800 Torr of CO, based on values for benzene (7.4 mM, 298°), chlorobenzene (6.4 mM, 293°), and chloroform (8.4 mM, 298°): (a) Linke, W. F. In Solubilities of Inorganic and Metal Organic Compounds, 4th ed.; D. Van Nostrand Co.: Princeton, NJ, 1958; Vol. 1, p 453. (b) Gerrard, W. Solubility of Gases and Liquids; Plenum Press: New York, 1976; p 141.
    • (1976) Solubility of Gases and Liquids , pp. 141
    • Gerrard, W.1
  • 23
    • 16944365137 scopus 로고    scopus 로고
    • note
    • 2(CO)Cl.
  • 24
    • 16944362979 scopus 로고    scopus 로고
    • note
    • The stoichiometric deoxygenation of selenium oxides by metal carbonyls has been reported previously; see ref 4.
  • 25
    • 16944363317 scopus 로고    scopus 로고
    • note
    • 3P appeared irreproducible, these alternatives were not further investigated.
  • 27
    • 16944365479 scopus 로고    scopus 로고
    • note
    • 3 is very small but at equilibrium the rates must be equal.
  • 30
    • 16944367014 scopus 로고    scopus 로고
    • note
    • 2 = 0.991 vs 0.995 for the one-term and two-term fits, respectively. It should be noted, however, that the smaller term is not an independent parameter, but is taken directly from eq 15; therefore, addition of the second term does not inherently lead to a better fit.
  • 31
    • 16944362681 scopus 로고    scopus 로고
    • note
    • 6, the values of ΔS‡ were -6.9(5) and -22.9(7) eu for E = Te and Se, respectively.
  • 32
    • 16944363288 scopus 로고    scopus 로고
    • note
    • 2SeO] = 20 mM).
  • 39
    • 16944363970 scopus 로고    scopus 로고
    • note
    • 3PO or CO.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.