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Volumn 38, Issue 31, 1997, Pages 5537-5540

Generation and reactions of difluorocyclopropyl anion

Author keywords

[No Author keywords available]

Indexed keywords

1 TRIMETHYLSILYL 2,2 DIFLUOROCYCLOPROPANE; ALDEHYDE; CYCLOPROPANE DERIVATIVE; REAGENT; TETRABUTYLAMMONIUM; UNCLASSIFIED DRUG;

EID: 0030797135     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01195-7     Document Type: Article
Times cited : (17)

References (18)
  • 5
    • 1842473809 scopus 로고    scopus 로고
    • Ojima, I.; McCarthy, J. R.; Welch, J. T. Eds. ACS, Washington, DC.
    • (b) Taguchi, T.; Shibuya, A.; Morikawa, T. ACS Symposium Series 639. Ojima, I.; McCarthy, J. R.; Welch, J. T. Eds. ACS, Washington, DC. 1996. pp 73-82.
    • (1996) ACS Symposium Series , vol.639 , pp. 73-82
    • Taguchi, T.1    Shibuya, A.2    Morikawa, T.3
  • 8
    • 0343535259 scopus 로고    scopus 로고
    • note
    • 3) : δ -78.1 (1F, dd, J = 149.0, 9.5 Hz), -55.9 (1F, ddd, J = 149.0, 14.2, 12.9 Hz).
  • 10
    • 0343971169 scopus 로고    scopus 로고
    • note
    • In DMF or DMI, TASF (4 mol%) promoted the reaction of trans-1 with benzaldehyde very slowly to give 3a in low yield along with recovery of trans-1.
  • 11
    • 0343971168 scopus 로고    scopus 로고
    • note
    • 19F-NMR.
  • 12
    • 0000602329 scopus 로고
    • Generation of α- and/or β-fluorinated carbanions through fluoride-mediated cleavage of carbon-silicon bonds and their reactions with electrophiles were reported. For examples: (a) Hiyama, T.; Obayashi, M.; Sawahata, M. Tetrahedron Lett. 1983, 24, 4113.
    • (1983) Tetrahedron Lett. , vol.24 , pp. 4113
    • Hiyama, T.1    Obayashi, M.2    Sawahata, M.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.