Cycloaddition reaction of 1-(4-nitrophenyl)-3-phenylnitrile ylide to buckminsterfullerene[60]

Tetrahedron Letters

Volumn 38, Issue 39, 1997, Pages 6933-6936

  Ovcharenko, A A ^a   Chertkov, V A ^a   Karchava, A V ^a   Yurovskaya, M A ^a  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE DERIVATIVE;

ARTICLE; CHEMICAL REACTION; COLUMN CHROMATOGRAPHY; DIASTEREOISOMER; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS;

EID: 0030762797     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01625-0     Document Type: Article

References (17)

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10. b) Averdung, J.; Mattay, J. Tetrahedron. 1996, 52, 5407
11. Muthu, S.; Maruthamuthu, P.; Ragunathan, R.; Vasudena Rao, P.R.; Mathews, C.K.; Tetrah.Lett. 1994, 35, 1763.
12. b) Matsubara, Y.; Tada, H.; Nagase, S.; Yoshida, Z. J.Org.Chem. 1995, 60, 5372
13. Huisgen, R.; Stangl, H.; Strum, H.J.; Raab, R.; Bunge, K. Chem.Ber. 1972, 105, 1258.
14. 3-C), 124.33 (2C), 128.54 (2C), 128.63, 128.94 (2C), 129.05, 129.15, 129.39, 129.49, 129.54, 129.59, 130.78 (2C), 131.05, 131.10, 134.34, 135.29, (2C), 140.15, 140.38, 140.43, 140.75 (2C), 141.07, 141.81, 142.17, 142.26, 142.37, 142.53, 142.59, 142.78, 142.96, 143.14, 143.20, 143.24, 143.29, 143.68, 144.46, 144.85, 144.92, 145.36, 145.43, 145.49, 145.60, 145.69, 145.79, 145.86, 145.89, 145.94, 145.99, 146.09, 146.30, 146.40, 146.47 (2C), 146.57, 146.84, 146.90, 147.24, 147.37, 147.45, 147.49, 148.42, 149.47, 149.55, 152.76, 155.32, 175.94 (C=N).
15. 3-C), 124.58, 128.86 (2C), 129.33, 129.83, 129.93, 131.41, 131.42 (2C), 131.89 (2C), 134.73, 134.86, 135.70, 136.63 (2C), 136.88, 140.49 (2C), 140.72, 141.09, 142.26, 142.30, 142.50, 142.57, 142.61 (2C), 142.76, 142.79, 142.82 (2C), 142.99, 143.25, 143.30, 143.32, 143.35, 143.74, 143,77, 144,60 (2C), 144.65, 144.80, 144.98, 145.36, 145.61 (2C), 145.72 (2C), 145.83, 145.93, 145.95, 146.10, 146.25, 146.39, 146.48, 146.50, 146.57, 146.60 (2C), 146.89, 146.94, 147.05, 147.55, 147.56, 147.70, 147.76 (2C), 148.00, 148.37, 149.05, 152.20, 155.30, 172.16 (C=N).
16. 2Ph)], the other protons signals cannot be distinguished from signals 3a.
17. 1H-NMR spectra of 2 and 3a are closely similar to that of toluene (see Hansen, M.; Jakobsen, H.J. J.Magn.Reson. 1975, 20, 520). The values of coupling constants for 2 and 3 will be reported.