The asymmetric reduction of ketones using chiral ammonium fluoride salts and silanes

Tetrahedron Letters

Volumn 38, Issue 33, 1997, Pages 5857-5860

  Drew, Mark D ^a   Lawrence, Nicholas J ^a   Watson, William ^b   Bowles, Stephen A ^c  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b Lancaster Synthesis Ltd   (United Kingdom)

^c British Biotechnology   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANOL; BENZYL ALCOHOL DERIVATIVE; CINCHONA ALKALOID;

ARTICLE; CATALYSIS; CHIRALITY; DRUG SYNTHESIS; IN VITRO STUDY; REACTION ANALYSIS; REDUCTION; STEREOCHEMISTRY;

CINCHONA;

EID: 0030749827     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(97)01445-7     Document Type: Article

References (20)

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20. The nucleophile involved in the "zipper" catalysis may, in principle, be the initial anion from NuR, or the hydride or alkoxide groups present on the polymer backbone. The intramolecular transfer need not be to the adjacent silicon atom. It is possible that 1,5-or indeed other types of intramolecular transfer are operating.