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85033821746
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note
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Theoretical calculations show that if the termination rate is a factor of 5000 less than the polymerization rate, 99.3% of monomer ultimately is converted to polymer; if the factor is dropped to 2000, ultimate conversion drops to 86.5%. Thus ultimate conversion of monomer is very sensitive to the ratio of the termination rate to polymerization rate; see ref 33.
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40
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85033808428
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note
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The deprotection of the benzyl groups of poly-1 and poly-2 leaves acid- and alchohol-substituted polymers that are identical with the products of ROMP of 4 and 6, respectively. We therefore have labeled the product polymers poly-4 and poly-6, respectively, although they are not synthesized by direct polymerization of 4 and 6.
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