Rapid Room Temperature Synthesis of Hexagonal Mesoporous Silica Using Inorganic Silicate Sources and Cationic Surfactants under Highly Acidic Conditions

Journal of Porous Materials

Volumn 4, Issue 2, 1997, Pages 129-134

  Setoguchi, Yukako M ^a   Teraoka, Yasutake ^a   Moriguchi, Isamu ^a   Kagawa, Shuichi ^a   Tomonaga, Nariyuki ^b   Yasutake, Akinori ^b   Izumi, Jun ^b  

^a NAGASAKI UNIVERSITY   (Japan)

^b MITSUBISHI HEAVY INDUSTRIES LTD   (Japan)

Author keywords

Acidic medium; Hexagonal phase; Inorganic silicate sources; Mesoporous silica; Room temperature; Synthesis

Indexed keywords

IONS; PH; POROSITY; POROUS MATERIALS; SILICATES; SURFACE ACTIVE AGENTS;

CATIONIC SURFACTANTS; MESOPOROUS MATERIALS;

SILICA;

EID: 0030609452     PISSN: 13802224     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1009684801918     Document Type: Article

References (20)

1. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, and J.S. Beck, Nature 359, 710 (1992).
2. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, and J.L. Schlenker, J. Am. Chem. Soc. 114, 10834 (1992).
3. P. Behrens and G.D. Stucky, Angew. Chem. Int. Ed. Engl. 32, 696 (1993).
4. M.E. Davis, C.-Y. Chen, S.L. Burkett, and R.F. Lobo, Mat. Res. Soc. Symp. Proc. 346, 831 (1994).
5. N.K. Raman, M.T. Anderson, and C.J. Brinker, Chem. Mater. 8, 1682 (1996).
6. P. Behrens, Angew. Chem. Int. Ed. Engl. 35, 515 (1996).
7. X.S. Zhao, G.Q. Lu, and G.L. Millar, Ind. Eng. Chem. Res. 35, 2075 (1996).
8. Q. Huo, D.L. Margolese, U. Ciesla, P. Feng, T.E. Gier, P. Sieger, R. Leon, P.M. Petroff, F. Schüth, and G.D. Stucky, Nature 368, 317 (1994).
9. A. Huo, D.I. Margolese, U. Ciesla, D.G. Demuth, P. Feng, T.E. Gier, P. Sieger, A. Firouzi, B.F. Chmelka, F. Schüth, and G.D. Stucky, Chem. Mater. 6, 1176 (1994).
10. P.T. Tanev and T.J. Pinnavaia, Science 267, 865 (1995).
11. D.M. Antonelli and J.Y. Ying, Angew. Chem. Int. Ed. Engl. 35, 426 (1996).
12. C.-Y. Chen, H.-X. Li, and M.E. Davis, Microporous Mater. 2, 17 (1993).
13. A. Monnier, F. Schüth, Q. Huo, D. Kumar, D. Margolese, R.S. Maxwell, G.D. Stucky, M. Krishnamurty, P. Petroff, A. Firouzi, M. Janicke, and B.F. Chmelka, Science 261, 1299 (1993).
14. G.D. Stucky, A. Monnier, F. Schüth, Q. Huo, D. Margolese, D. Kumar, M. Krishnamurty, P. Petroff, A. Firouzi, M. Janicke, and B.F. Chmelka, Mol. Cryst. Liq. Cryst. 240, 187 (1994).
15. K.J. Edler and J.W. White, J. Chem. Soc., Chem. Commun. 155 (1995).
16. P.T. Tanev, M. Chibwe, and T.J. Pinnavaia, Nature 368, 321 (1994).
17. R. Szostak, Molecular Sieves. Principles of Synthesis and Identification (Van Nostrand Reinhold, New York, 1989), p. 143.
18. E. Lippmaa, M. Mägi, A. Samoson, G. Engelhardt, and A.-R. Grimmer, J. Am. Chem. Soc. 102, 4889 (1980).
19. A. Steel, S.W. Carr, and M.W. Anderson, Chem. Mater. 7, 1829 (1995).
20. A. Firouzi, D. Kumar, L.M. Bull, T. Besier, P. Sieger, Q. Huo, S.A. Walker, J.A. Zasadzinski, C. Glinka, J. Nicol, D. Margolese, G.D. Stucky, and B.F. Chmelka, Science 267, 1138 (1995).