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unpublished.
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K. F. Freed (unpublished).
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85033043538
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ν, as explained in Ref. 19.
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ν, as explained in Ref. 19.
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50
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85033050182
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note
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0(z) = cδ(z) and c<0, along with methods for rectifying these problems. Since these corrections amount to modifying the spatial dimension d in the effective "diffusion coefficient" (l/2d) to be a function of c, these modifications may readily be combined with the results presented here for surface segregation.
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54
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36549092416
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λ,λ are now dependent on both composition and density and are, therefore, varying through the density profile. A simplified representation ensues by using Eq. (35) only as the bulk interaction parameters and ignoring their near surface variation. Similarly, the use of more realistic models for the translational entropy [see, for instance, Ref. 14 and R. Dickman and C. K. Hall, J. Chem. Phys. 85, 4108 (1986);
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H.-P. Deutsch and R. Dickman, ibid. 93, 8983 (1990)] leads to nonlinear integral equations for the density profiles and, hence, to the loss of analytical tractability.
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Deutsch, H.-P.1
Dickman, R.2
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