Chiral conjugated propeller polymers

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

Volumn 37, Issue 2, 1996, Pages 462-463

  Ma, Liang ^a   Hu, Qiao Sheng ^a   Vitharana, Dilrukshi ^a   Pu, Lin ^a  

^a NORTH DAKOTA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; CHEMICAL BONDS; FLUORESCENCE; GEL PERMEATION CHROMATOGRAPHY; INFRARED SPECTROSCOPY; MOLECULAR WEIGHT; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; ULTRAVIOLET SPECTROSCOPY;

CHIRAL PROPELLER POLYMERS; CIRCULAR DICHROISM (CD) SPECTRUM;

FLUORINE CONTAINING POLYMERS;

EID: 0030204332     PISSN: 00323934     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Article

References (23)

1. Skotheim, T. A., Ed. Handbook of Conducting Polymers, Vol. 1 and 2; Marcel Dekker: New York, 1986.
2. (a) Kiess, H. G. Ed. Conjugated Conducting Polymers; Springer-Verlag: New York, 1992.
3. (b) Bredas, J. L.; Silbey, R. Conjugated Polymers: The Novel Science and Technologh of Highly Conducting and Nonlinear Optically Active Materials; Kluwer Academic Publishers: Boston, 1991.
4. Several conjugated polymers with chiral side chain substituents are known: (a) Moore, J. S.; Gorman, C. B.; Grubbs, R. H. J. Am. Chem. Soc. 1991, 113, 1704. (b) Kotkar, D.; Joshi, V.; Ghosh, P. J. Chem. Soc., Chem. Commun. 1988, 917. (c) Lemaire, M.; Delabouglise, D.; Garreau, R.; Guy, A.; Roncali, J. J. Chem. Soc., Chem. Commun. 1988, 658.. (d) Salmon, M.; Biden, G. J. Electrochem. Soc.: Electrochem. Sci. & Tech. 1985, 1897.
5. Several conjugated polymers with chiral side chain substituents are known: (a) Moore, J. S.; Gorman, C. B.; Grubbs, R. H. J. Am. Chem. Soc. 1991, 113, 1704. (b) Kotkar, D.; Joshi, V.; Ghosh, P. J. Chem. Soc., Chem. Commun. 1988, 917. (c) Lemaire, M.; Delabouglise, D.; Garreau, R.; Guy, A.; Roncali, J. J. Chem. Soc., Chem. Commun. 1988, 658.. (d) Salmon, M.; Biden, G. J. Electrochem. Soc.: Electrochem. Sci. & Tech. 1985, 1897.
6. Several conjugated polymers with chiral side chain substituents are known: (a) Moore, J. S.; Gorman, C. B.; Grubbs, R. H. J. Am. Chem. Soc. 1991, 113, 1704. (b) Kotkar, D.; Joshi, V.; Ghosh, P. J. Chem. Soc., Chem. Commun. 1988, 917. (c) Lemaire, M.; Delabouglise, D.; Garreau, R.; Guy, A.; Roncali, J. J. Chem. Soc., Chem. Commun. 1988, 658.. (d) Salmon, M.; Biden, G. J. Electrochem. Soc.: Electrochem. Sci. & Tech. 1985, 1897.
7. Several conjugated polymers with chiral side chain substituents are known: (a) Moore, J. S.; Gorman, C. B.; Grubbs, R. H. J. Am. Chem. Soc. 1991, 113, 1704. (b) Kotkar, D.; Joshi, V.; Ghosh, P. J. Chem. Soc., Chem. Commun. 1988, 917. (c) Lemaire, M.; Delabouglise, D.; Garreau, R.; Guy, A.; Roncali, J. J. Chem. Soc., Chem. Commun. 1988, 658.. (d) Salmon, M.; Biden, G. J. Electrochem. Soc.: Electrochem. Sci. & Tech. 1985, 1897.
8. Hu, Q. -S.; Vitharana, D.; Liu, G. -Y.; Jain, V.; Wagaman, M. M.; Zhang, L.; Lee, T. R.; Pu, L. Macromolecules 1996, 29, 1082.
9. Hu, Q. -S.; Vitharana, D.; Liu, G. -Y.; Jain, V.; Pu, L. Manuscript submitted.
10. Ma, L.; Hu, Q. -S.; Musick, K. Y.; Vitharana, D.; Wu, C.; Kwan, C. M. S.; Pu. L. Manuscript submitted.
11. For examples of the Suzuki coupling reaction, see: (a) Miyaura, N.; Yanagi, T.; Suruki, A. Synth.Comm. 1981, 11, 513. (b) Wallow, T. I.; Novak, B. M. J. Am. Chem. Soc. 1991. 113, 7411. (c) Suzuki, A. Acc. Chem. Res. 1982, 15, 178. (d) Huber, J.; Scherf, U. Macromol. Rapid Commun. 1994, 15, 897.
12. For examples of the Suzuki coupling reaction, see: (a) Miyaura, N.; Yanagi, T.; Suruki, A. Synth.Comm. 1981, 11, 513. (b) Wallow, T. I.; Novak, B. M. J. Am. Chem. Soc. 1991. 113, 7411. (c) Suzuki, A. Acc. Chem. Res. 1982, 15, 178. (d) Huber, J.; Scherf, U. Macromol. Rapid Commun. 1994, 15, 897.
13. For examples of the Suzuki coupling reaction, see: (a) Miyaura, N.; Yanagi, T.; Suruki, A. Synth.Comm. 1981, 11, 513. (b) Wallow, T. I.; Novak, B. M. J. Am. Chem. Soc. 1991. 113, 7411. (c) Suzuki, A. Acc. Chem. Res. 1982, 15, 178. (d) Huber, J.; Scherf, U. Macromol. Rapid Commun. 1994, 15, 897.
14. For examples of the Suzuki coupling reaction, see: (a) Miyaura, N.; Yanagi, T.; Suruki, A. Synth.Comm. 1981, 11, 513. (b) Wallow, T. I.; Novak, B. M. J. Am. Chem. Soc. 1991. 113, 7411. (c) Suzuki, A. Acc. Chem. Res. 1982, 15, 178. (d) Huber, J.; Scherf, U. Macromol. Rapid Commun. 1994, 15, 897.
15. For selected references on the synthesis of poly(aryleneethynylene) using the Heck coupling reactions, see: (a) Kondo, K.; Okuda, M.; Fujitani, T. Macromolecules 1993, 26, 7382. (b) Yamamoto, T.; Yamada, W.; Tikagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620. (c) Yamamoto, T.; Takagi, M.; Kizu, K.; Maruyama, T.; Kubota, K.; Kanbara, H.; Kurihara, T.; Kaino, T. J. Chem. Soc. Chem. Commun. 1993, 797. (d) Melissaris, A. P.; Litt, M. H. Macromolecules 1994, 27, 883. (e) Moroni, M.; Moigne, J. L.; Luzzati, S. Macromolecules 1994, 27, 562. (f) Zhou, Q.; Swager, T. S. J. Am. Chem. Soc. 1995, 117, 7017.
16. For selected references on the synthesis of poly(aryleneethynylene) using the Heck coupling reactions, see: (a) Kondo, K.; Okuda, M.; Fujitani, T. Macromolecules 1993, 26, 7382. (b) Yamamoto, T.; Yamada, W.; Tikagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620. (c) Yamamoto, T.; Takagi, M.; Kizu, K.; Maruyama, T.; Kubota, K.; Kanbara, H.; Kurihara, T.; Kaino, T. J. Chem. Soc. Chem. Commun. 1993, 797. (d) Melissaris, A. P.; Litt, M. H. Macromolecules 1994, 27, 883. (e) Moroni, M.; Moigne, J. L.; Luzzati, S. Macromolecules 1994, 27, 562. (f) Zhou, Q.; Swager, T. S. J. Am. Chem. Soc. 1995, 117, 7017.
17. For selected references on the synthesis of poly(aryleneethynylene) using the Heck coupling reactions, see: (a) Kondo, K.; Okuda, M.; Fujitani, T. Macromolecules 1993, 26, 7382. (b) Yamamoto, T.; Yamada, W.; Tikagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620. (c) Yamamoto, T.; Takagi, M.; Kizu, K.; Maruyama, T.; Kubota, K.; Kanbara, H.; Kurihara, T.; Kaino, T. J. Chem. Soc. Chem. Commun. 1993, 797. (d) Melissaris, A. P.; Litt, M. H. Macromolecules 1994, 27, 883. (e) Moroni, M.; Moigne, J. L.; Luzzati, S. Macromolecules 1994, 27, 562. (f) Zhou, Q.; Swager, T. S. J. Am. Chem. Soc. 1995, 117, 7017.
18. For selected references on the synthesis of poly(aryleneethynylene) using the Heck coupling reactions, see: (a) Kondo, K.; Okuda, M.; Fujitani, T. Macromolecules 1993, 26, 7382. (b) Yamamoto, T.; Yamada, W.; Tikagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620. (c) Yamamoto, T.; Takagi, M.; Kizu, K.; Maruyama, T.; Kubota, K.; Kanbara, H.; Kurihara, T.; Kaino, T. J. Chem. Soc. Chem. Commun. 1993, 797. (d) Melissaris, A. P.; Litt, M. H. Macromolecules 1994, 27, 883. (e) Moroni, M.; Moigne, J. L.; Luzzati, S. Macromolecules 1994, 27, 562. (f) Zhou, Q.; Swager, T. S. J. Am. Chem. Soc. 1995, 117, 7017.
19. For selected references on the synthesis of poly(aryleneethynylene) using the Heck coupling reactions, see: (a) Kondo, K.; Okuda, M.; Fujitani, T. Macromolecules 1993, 26, 7382. (b) Yamamoto, T.; Yamada, W.; Tikagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620. (c) Yamamoto, T.; Takagi, M.; Kizu, K.; Maruyama, T.; Kubota, K.; Kanbara, H.; Kurihara, T.; Kaino, T. J. Chem. Soc. Chem. Commun. 1993, 797. (d) Melissaris, A. P.; Litt, M. H. Macromolecules 1994, 27, 883. (e) Moroni, M.; Moigne, J. L.; Luzzati, S. Macromolecules 1994, 27, 562. (f) Zhou, Q.; Swager, T. S. J. Am. Chem. Soc. 1995, 117, 7017.
20. For selected references on the synthesis of poly(aryleneethynylene) using the Heck coupling reactions, see: (a) Kondo, K.; Okuda, M.; Fujitani, T. Macromolecules 1993, 26, 7382. (b) Yamamoto, T.; Yamada, W.; Tikagi, M.; Kizu, K.; Maruyama, T.; Ooba, N.; Tomaru, S.; Kurihara, T.; Kaino, T.; Kubota, K. Macromolecules 1994, 27, 6620. (c) Yamamoto, T.; Takagi, M.; Kizu, K.; Maruyama, T.; Kubota, K.; Kanbara, H.; Kurihara, T.; Kaino, T. J. Chem. Soc. Chem. Commun. 1993, 797. (d) Melissaris, A. P.; Litt, M. H. Macromolecules 1994, 27, 883. (e) Moroni, M.; Moigne, J. L.; Luzzati, S. Macromolecules 1994, 27, 562. (f) Zhou, Q.; Swager, T. S. J. Am. Chem. Soc. 1995, 117, 7017.
21. Ma, L.; Hu, Q. -S.; Vitharana, D.; Pu, L. Manuscript submitted.
22. 10: Propeller octopolar molecules have shown very good secondorder nonlinear optical properties: Dhenaut, C.; Ledoux, I.; Samuel, I. D. W.; Zyss, J.; Bourgault, M.; Bozec, H. L. Nature 1995, 374, 339.
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