Large Deformation Rheology of Gelatin Gels

Polymer Gels and Networks

Volumn 4, Issue 3, 1996, Pages 189-227

  Bot, Arjen ^a   Van Amerongen, Ivo A ^a   Groot, Robert D ^a,b   Hoekstra, Niko L ^a   Agterof, Wim G M ^a  

^a UNILEVER RESEARCH VLAARDINGEN   (Netherlands)

^b UNILEVER RESEARCH   (United Kingdom)

Author keywords

Biopolymer; Fracture; Gel; Gelatin; Protein; Rupture

Indexed keywords

BIOPOLYMERS; CHEMICAL BONDS; COMPACTION; ELASTIC MODULI; ELASTICITY; FRACTURE; PROTEINS; RHEOLOGY; SHEAR DEFORMATION; STRAIN; STRESSES;

BREAKING STRAIN; BREAKING STRESS; GELATIN GELS; LARGE DEFORMATIONS; LINEAR ELASTIC PROPERTIES; NONLINEAR ELASTIC PROPERTIES; RUPTURE; STRESS STRAIN CURVES;

GELS;

EID: 0030170291     PISSN: 09667822     EISSN: None     Source Type: Journal    
DOI: 10.1016/0966-7822(96)00011-1     Document Type: Article

References (37)

1. Clark, A. H. & Ross-Murphy, S. B., Structural and mechanical properties of biopolymer gels. Adv. Polym. Sci., 83 (1987) 57-192.
2. van Vliet T. & Walstra P., Large deformation and fracture behaviour of gels, Faraday Discuss, 101 (1995) 359-370.
3. Bot A., Groot, R. D. & Agterof, W. G. M., Non-linear elasticity and rupture of gelatin gels, in Gums and stabilisers for the food industry 8 (Edited by G. O. Phillips, P. A. Williams & D. J. Wedlock). IRL Press, Oxford, 1996, 117-126.
4. Pezron, I., Djabourov, M. & Leblond, J., Conformation of gelatin chains in aqueous solutions: 1. A light and small-angle neutron scattering study. Polymer, 32 (1991) 3201-3210.
5. Herning, T., Djabourov, M., Leblond, J. & Takerkart, G., Conformation of gelatin chains in aqueous solutions: 2. A quasi-elastic light scattering study. Polymer, 32 (1991) 3211-3217.
6. Djabourov, M., Bonnet, N., Kaplan, H., Favard, N., Favard, P., Lechaire, J.P. & Maillard, M., 3D analysis of gelatin gel networks from transmission electron microscopy imaging. J. Phys. II (France), 3 (1993) 611-624.
7. Bot, A., Schram, R. P. C. & Wegdam, G. H., Brillouin light scattering from a biopolymer gel: hypersonic sound waves in gelatin. Colloid Polym. Sci., 273 (1995) 252-256.
8. te Nijenhuis, K., Investigation into the ageing process in gels of gelatin/water systems by the measurement of their dynamic moduli. Part I - Phenomenology. Colloid Polym. Sci., 259 (1981) 522-535.
9. te Nijenhuis, K., Investigation into the ageing process in gels of gelatin/water systems by the measurement of their dynamic moduli. Part II - Mechanism of the ageing process. Colloid Polym. Sci., 259 (1981) 1017-1026.
10. Carnali, J. O., Gelation in physically associating biopolymer systems. Rheol. Acta, 31 (1992) 399-412.
11. McEvoy, H., Ross-Murphy, S. B. & Clark, A. H., Large deformation and ultimate properties of biopolymer gels: 1. Single biopolymer component systems. Polymer, 26 (1985) 1483-1492.
12. Groot, R. D., Bot, A. & Agterof, W. G. M., Molecular theory of strain hardening of a polymer gel; Application to gelatin. J. Chem. Phys., 104 (1996) 9202-9219.
13. Groot R. D., Bot, A. & Agterof, W. G. M., Molecular theory of the yield behaviour of a polymer gel; Application to gelatin. J. Chem. Phys., 104 (1996) 9220-9233.
14. Blatz, P. J., Sharda, S. C. & Tschoegl, N. W., Strain energy function for rubberlike materials based on a generalized measure of strain. Trans. Soc. Rheol., 18 (1974) 145-161.
15. CRC Handbook of chemistry and physics, (Edited by D. R. Lide) 74th Edition. CRC Press, Boca Raton, FL, 1993, 8-42.
16. Groot, R. D. & Agterof, W. G. M., Dynamic viscoelastic modulus of associative polymer networks: off-lattice simulations, theory and comparison to experiments. Macromolecules, 28 (1995) 6284-6295.
17. Nakakura, H., Nishigaki, F., Sambuichi, M., Miura, Y. & Osasa, K., Studies on mechanical compression properties of gels. Nippon Shokuhin Kogyo Gakkaishi, 39 (1992) 8-15.
18. Kohlrausch, F., Praktische Physik, Vol. 1, Teubner Verlagsgesellschaft, Stuttgart, 1960, p. 158.
19. Ferry, J. D., Mechanical properties of substances of high molecular weight. IV. Rigidities of gelatin gels; dependence on concentration, temperature and molecular weight. J. Am. Chem. Soc., 70 (1948) 2244-2249.
20. Bot, A., van Amerongen, I. A., Groot, R. D., Hoekstra, L. L. & Agterof, W. G. M., Effect of deformation rate on the stress-strain curves of gelatin gels, J. Chim. Physique, 93 (1996) 837-849.
21. Veis, A., The macromolecular chemistry of gelatin. Academic Press, New York, 1964.
22. Gerasimov, V. K. & Trapeznikov, A. A., Influence of concentration of hydrogen ions in the presence of chloride and citrate ions on the strength, reversible deformation, and shear modulus of gelatin gels. Colloid J. USSR, 44 (1982) 186-190.
23. Johnston-Banks, F. A., Gelatin, in Food gels, (Edited by P. Harris). Elsevier, Barking, UK, 1990, 233-289.
24. Bello, J., Riese, H. C. A. & Vinograd, J. R., Mechanism of gelation of gelatin. Influence of certain electrolytes on the melting points of gels of gelatin and chemically modified gelatins. J. Phys. Chem., 60 (1956) 1299-1306.
25. Flory, P. J., Principles of polymer chemistry. Cornell University Press, Ithaca, 1953.
26. Treloar, L. R. G., The physics of rubber elasticity, Third Edition. Clarendon, Oxford, 1975, Chapter 6.
27. James, H. M. & Guth, E., Theory of the increase in rigidity of rubber during cure. J. Chem. Phys., 15 (1947) 669-683.
28. Edwards, S. F. & Vilgis, T., The effect of entanglements in rubber elasticity. Polymer, 27 (1986) 483-492.
29. Groot, R. D. & Agterof, W. G. M., Monte-Carlo study of associative polymer networks. I. Equation of state. J. Chem. Phys., 100 (1994) 1649-1656.
30. Groot, R. D. & Agterof, W. G. M., Monte-Carlo study of associative polymer networks. II. Rheologic aspects. J. Chem. Phys., 100 (1994) 1657-1664.
31. Pezron, I., Herning, T., Djabourov, M. & Leblond, J., Scattering from a biopolymer solution in the sol and gel states: the gelatin example, in Physical networks, (Edited by W. Burchard & S. B. Ross-Murphy). Elsevier Applied Science, Barking, UK, 1990, 231-252.
32. Petruccione, F. & Biller, P., A numerical stochastic approach to network theories of polymeric fluids. J. Chem. Phys., 89 (1988) 577-582.
33. Biller, P. & Petruccione, F., Continuous time simulation of transient polymer network models. J. Chem. Phys., 92 (1990) 6322-6326.
34. Ledward, D. A., Gelation of gelatin, in Functional properties of food macromolecules, (Edited by J. R. Mitchell & D. A. Ledward). Elsevier Applied Science, Barking, UK, 1986, 171-201.
35. Stevens, M. J. & Kremer, K., The nature of flexible polyelectrolytes in salt free solution: a molecular dynamics study. J. Chem. Phys., 103 (1995) 1669-1690.
36. Sasaki, S., Ojima, H., Yataki, K. & Maeda, H., Flory exponent of the chain of the expanding polyion gel. J. Chem. Phys., 102 (1995) 9694-9699.
37. Love, A. E. H., A treatise on the mathematical theory of elasticity, Fourth Edition. Cambridge University Press, Cambridge, 1927.