Synthesis, structure, and deprotonation of a mesitylphosphido-bridged cyclopentadienylnickel(II) dimer

Organometallics

Volumn 15, Issue 10, 1996, Pages 2483-2488

  Maslennikov, Stanislav V ^a   Glueck, David S ^a   Yap, Glenn P A ^b   Rheingold, Arnold L ^b  

^a Dartmouth College   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0012465725     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950982u     Document Type: Article

References (35)

1. Carty, A. J.; MacLaughlin, S. A.; Nucciarone, D. In Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis; Verkade, J. G., Quin, L. D., Ed.; VCH: Deerfield Beach, FL, 1987; pp 559-619.
2. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
3. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
4. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
5. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
6. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
7. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
8. For some recent examples and leading references, see: (a) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1994, 13, 401-403. (b) Bleeke, J. R.; Rohde, A. M.; Robinson, K. D. Organometallics 1995, 14, 1674-1680. (c) Haupt, H.-J.; Schwefer, M.; Florke, U. Inorg. Chem. 1995, 34, 292-297. (d) Hey-Hawkins, E.; Kurz, S.; Sieler J.; Baum, G. J. Organomet. Chem. 1995, 486, 229-235. (e) Kourkine, I. V.; Chapman, M. B.; Glueck, D. S.; Eichele, K.; Wasylishen, R. E.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L. Inorg. Chem. 1996, 35, 1478-1485. See also: (f) Jones, R. A.; Norman, N. C.; Seeberger, M. H.; Atwood, J. L.; Hunter, W. E. Organometallics 1983, 2, 1629-1634. (g) Jones, R. A.; Seeberger, M. H. Inorg. Synth. 1989, 25, 173-177.
9. (a) Lorenz, I.-P.; Pohl, W.; Noth, H.; Schmidt, M. J. Organomet. Chem. 1994, 475, 211-221.
10. (b) Ho, J.; Drake, R. J.; Stephan, D. W. Organometallics 1993, 115, 3792-3793.
11. (c) Hirth, U.-A.; Malisch, W. J. Organomet. Chem. 1992, 439, C16-C19.
12. (d) Seyferth, D.; Wood, T. G.; Henderson, R. S. J. Organomet. Chem. 1987, 336, 163-182.
13. (e) Bartsch, R.; Hietkamp, S.; Morton, S.; Stelzer, O. J. Organomet. Chem. 1981, 222, 263-273.
14. (f) Treichel, P. M.; Douglas, W. M.; Dean, W. K. Inorg. Chem. 1972, 11, 1615-1618.
15. Dobbie, R. C.; Green, M. A.; Stone, F. G. A. J. Chem. Soc. A 1969, 1881-1882.
16. For analysis of related NMR spin systems involving P-H bonds, see: (a) Palmer, R. A.; Whitcomb, D. R. J. Magn. Reson. 1980, 39, 371-379. (b) Pasquali, M.; Marchetti, F.; Leoni, P.; Beringhelli, T.; D'Alfonso, G. Gazz. Chim. Ital. 1993, 123, 659-664.
17. For analysis of related NMR spin systems involving P-H bonds, see: (a) Palmer, R. A.; Whitcomb, D. R. J. Magn. Reson. 1980, 39, 371-379. (b) Pasquali, M.; Marchetti, F.; Leoni, P.; Beringhelli, T.; D'Alfonso, G. Gazz. Chim. Ital. 1993, 123, 659-664.
18. Schafer, H.; Zipfel, J.; Migula, B.; Binder, D. Z. Anorg. Allg. Chem. 1983, 501, 111-120.
19. Sergeyev, N. M. In Isotope Effects in NMR Spectroscopy; Diehl, P., Fluck, E., Günther, H., Kosfeld, R., Selig, J., Eds.; Springer Verlag: Berlin, 1990; p 42.
20. Coleman, J. M.; Dahl, L. F. J. Am. Chem. Soc. 1967, 89, 542-552.
21. (a) Tolman, C. A. Chem. Rev. 1977, 77, 313-348.
22. 2Mes was measured using Tolman's method for unsymmetrical phosphines.
23. Friebolin, H. Basic One- and Two-Dimensional NMR Spectroscopy; VCH: New York, 1991; pp 263-275.
24. Holland, P. L.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1996, 118, 1092-1104.
25. For related reports of isomerism in bridged primary phosphide complexes, see ref 2a,b,e and: (a) Clegg, W.; Morton, S. Inorg. Chem. 1979, 18, 1189-1192. (b) Brown, M. P.; Buckett, J.; Harding, M. M.; Lynden-Bell, R. M.; Mays, M. J.; Woulfe, K. W. J. Chem. Soc., Dalton Trans. 1991, 3097-3102. (c) Manojlovic-Muir, L.; Muir, K. W.; Jennings, M. C.; Mays, M. J.; Solan, G. A.; Woulfe, K. W. J. Organomet. Chem. 1995, 491, 255-262.
26. For related reports of isomerism in bridged primary phosphide complexes, see ref 2a,b,e and: (a) Clegg, W.; Morton, S. Inorg. Chem. 1979, 18, 1189-1192. (b) Brown, M. P.; Buckett, J.; Harding, M. M.; Lynden-Bell, R. M.; Mays, M. J.; Woulfe, K. W. J. Chem. Soc., Dalton Trans. 1991, 3097-3102. (c) Manojlovic-Muir, L.; Muir, K. W.; Jennings, M. C.; Mays, M. J.; Solan, G. A.; Woulfe, K. W. J. Organomet. Chem. 1995, 491, 255-262.
27. For related reports of isomerism in bridged primary phosphide complexes, see ref 2a,b,e and: (a) Clegg, W.; Morton, S. Inorg. Chem. 1979, 18, 1189-1192. (b) Brown, M. P.; Buckett, J.; Harding, M. M.; Lynden-Bell, R. M.; Mays, M. J.; Woulfe, K. W. J. Chem. Soc., Dalton Trans. 1991, 3097-3102. (c) Manojlovic-Muir, L.; Muir, K. W.; Jennings, M. C.; Mays, M. J.; Solan, G. A.; Woulfe, K. W. J. Organomet. Chem. 1995, 491, 255-262.
28. Ho, J.; Hou, Z.; Drake, R. J.; Stephan, D. W. Organometallics 1993, 12, 3145-3157.
29. (a) Bautista, M. T.; Jordan, M. R.; White, P. S.; Schauer, C. K. Inorg. Chem. 1993, 32, 5429-5430 and references therein.
30. (b) Moser, E.; Fischer, E. O. J. Organomet. Chem. 1968, 15, 157-163.
31. (c) See also: Deeming, A. J.; Doherty, S.; Marshall, J. E.; Powell, J. L.; Senior, A. M. J. Chem. Soc., Dalton Trans. 1993, 1093-1100.
32. Dessy, R. E.; Kornmann, R.; Smith, C.; Hayter, R. J. Am. Chem. Soc. 1968, 90, 2001-2004.
33. (a) Hayter, R. G. J. Am. Chem. Soc. 1963, 85, 3120-3124.
34. (b) Reference 12b and references therein.
35. Bartlett, R. A.; Olmstead, M. M.; Power, P. P.; Sigel, G. A. Inorg. Chem. 1987, 26, 1941-1946.