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Volumn 71, Issue 8, 1998, Pages 1857-1862

Electronic Effect of Substituents on Cyclopalladation of the Solvated Palladium(II) Complexes with N-Benzyl Triamine [Pd(Sol){(4-XC6H4CH2)NH(CH2) 3NR(CH2)3NH2}]2+ (Sol = Solvent; R = Ph, H, and Me; X = H, Et, Me, MeO, Cl, and NO2)

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EID: 0011516030     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.71.1857     Document Type: Article
Times cited : (19)

References (22)
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    • A. J. Deeming and I. P. Rothwell, Pure Appl. Chem., 52, 649 (1980); A. J. Deeming and I. P. Rothwell, J. Organomet. Chem., 205, 117 (1981); P. L. Alsters, P. F. Engel, M. P. Hogerheide, M. Copijn, A. L. Spek, and G. van Koten, Organometallics, 12, 1831 (1993); J. Vicente, I. Saura-Llamas, and P. G. Jones, J. Chem. Soc., Dalton Trans., 1993, 3619; J.-M. Valk, F. Maassarani, P. van der Sluis, A. L. Spek, J. Boersma, and G. van Koten, Organometallics, 13, 2320 (1994); A. J. Canty and G. van Koten, Acc. Chem. Res., 28, 406 (1995); A. D. Ryabov, Chem. Rev., 90, 403 (1990), and references therein.
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    • A. J. Deeming and I. P. Rothwell, Pure Appl. Chem., 52, 649 (1980); A. J. Deeming and I. P. Rothwell, J. Organomet. Chem., 205, 117 (1981); P. L. Alsters, P. F. Engel, M. P. Hogerheide, M. Copijn, A. L. Spek, and G. van Koten, Organometallics, 12, 1831 (1993); J. Vicente, I. Saura-Llamas, and P. G. Jones, J. Chem. Soc., Dalton Trans., 1993, 3619; J.-M. Valk, F. Maassarani, P. van der Sluis, A. L. Spek, J. Boersma, and G. van Koten, Organometallics, 13, 2320 (1994); A. J. Canty and G. van Koten, Acc. Chem. Res., 28, 406 (1995); A. D. Ryabov, Chem. Rev., 90, 403 (1990), and references therein.
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    • and references therein
    • A. J. Deeming and I. P. Rothwell, Pure Appl. Chem., 52, 649 (1980); A. J. Deeming and I. P. Rothwell, J. Organomet. Chem., 205, 117 (1981); P. L. Alsters, P. F. Engel, M. P. Hogerheide, M. Copijn, A. L. Spek, and G. van Koten, Organometallics, 12, 1831 (1993); J. Vicente, I. Saura-Llamas, and P. G. Jones, J. Chem. Soc., Dalton Trans., 1993, 3619; J.-M. Valk, F. Maassarani, P. van der Sluis, A. L. Spek, J. Boersma, and G. van Koten, Organometallics, 13, 2320 (1994); A. J. Canty and G. van Koten, Acc. Chem. Res., 28, 406 (1995); A. D. Ryabov, Chem. Rev., 90, 403 (1990), and references therein.
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    • 1HNMR spectral changes also indicated no side reactions
    • 1HNMR spectral changes also indicated no side reactions.
  • 22
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    • note
    • In Ref. 9, we have reported the dependence of the rate constant for the cyclopalladation on the concentration of dimethyl sulfoxide in nitromethane, the kinetic isotope effect, and the solvent effect.


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