Mechanistic Studies on Cyclopalladation of the Solvated Palladium (II) Complexes with N-Benzyl Triamine Ligands in Various Solvents. Crystal Structures of [Pd(Sol)(Bn2Medptn)](BF4)2 (Sol = Acetonitrile and N, N-Dimethylformamide; Bn2Medptn = N, N′-Dibenzyl-4-methyl-4-azaheptane-1,7-diamine) and [Pd(H-1Bn2Medptn-C, N

Bulletin of the Chemical Society of Japan

Volumn 71, Issue 3, 1998, Pages 619-629

  Yagyu, Takeyoshi ^a   Aizawa, Sen Ichi ^a,b   Funahashi, Shigenobu ^a  

^a NAGOYA UNIVERSITY   (Japan)

^b SHIZUOKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000051509     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.71.619     Document Type: Article

References (37)

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28. The coordinated acetonitrile of 1 in deuterated nitromethane shows a singlet at 2.3 ppm as described in Experimental section.
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30. This side reaction may come from decomposition of palladium(II) complexes due to the hydrolysis of DMF or DMSO.
31. The reaction was complete within 30 s in the preliminary measurements using a quartz cuvette with a Teflon® cap.
32. -.
33. 1H NMR spectrum for 3.
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37. z orbital is operative as is general with the associative mechanism for the Pd(II) complexes.