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(a) Unpublished work of Dr. K. Kim.
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13
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(a) For a discussion of this effect, see Sanders, J. K. M.; Hunter, B. K. Modern NMR Spectroscopy; Oxford University Press: Oxford, 1987; pp 299-302.
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23
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85034476790
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note
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(b) The same effect is seen in simpler 5-(alkyloxy)thianthreniumyl perchlorates in which the alkyl group has a stereogenic center attached to oxygen, such as 2-pentyl and 2-hexyl. The effect is absent where the alkyl group is, for example, methyl, ethyl, isopropyl. Unpublished work of W. Zhao.
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26
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21144460962
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and references therein
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Ternay, A. L., Jr.; Baack, J.; Lam, W. W. Phosphorus, Sulfur Silicon 1992, 70, 19, and references therein.
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33
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85034471840
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note
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25 Our assignments were confirmed, also, by the NMR data for 5j,k and by Ortep data not only for 5j, but also for the solid, trans,trans alcohol itself (see Figure 5 in the Supporting Information).
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35
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0347869828
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Li, S.; Allinger, N. L. Tetrahedron 1988, 44, 1339. The origin of the alcohols and the NMR solvent are not given.
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