Stereochemical control of N,N-disubstitution in alkynylaminocarbene complexes of chromium(O) and tungsten(O)

Organometallics

Volumn 15, Issue 16, 1996, Pages 3611-3615

  Sabaté, Ramon ^a   Schick, Ute ^a   Moretó, Josep M ^a   Ricart, Susagna ^a  

^a DEPT OF ENVIRONMENTAL CHEMISTRY   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0009078022     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960159d     Document Type: Article

References (25)

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17. Addition of 15 μL (approximately 2 drops) of water into the reaction mixture.
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19. The acidity of the protons of the methylenic group linked to the nitrogen may account for the rearrangement of the propargilic group to an allenic one. The structure proposed for these compounds is as follows: equation presented
20. Secondary allyl bromide gave only 10% yield of the expected product 2k when NaH (2 or 3 equiv) was used.
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