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Cs=0.04 are not clearly understood at the present time. Although it is noteworthy that the larger Cs 3d binding energy observed at the initial Cs coverage is consistent with stronger surface dipole expected in the absence of the depolarization effect at initial coverages, a careful examination of both initial- and final-state contributions on the observed binding energy at the initial Cs coverage is necessary. On the other hand, it is unlikely that the observed binding energy of the Cs 3d core level at the initial Cs coverage results from the presence of impurities such as ambient gases of oxygen, CO or water below the detection level since the binding energy shift of Cs would be toward lower binding energy side; see Refs. 35, 36.
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0001529532
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The simple charge transfer model would fail to explain the binding energy shifts toward lower binding energy observed in the oxidation of alkali metals including Cs in this study. A more accurate account of the experimental core level shifts must include the final state effect, and the negative binding energy shifts can be explained by the point charge model proposed by P. H. Citrin and T. D. Thomas, J. Chem. Phys. 57, 4446 (1972).
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65
-
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85034504156
-
-
note
-
2(0002) surface and the change in the work function (Δφ= -1.75eV) after the Cs adsorption, which were both experimentally measured using the low kinetic energy cutoff of our photoelectron spectrum.
-
-
-
-
67
-
-
85034513382
-
-
- was replaced with the value of -3.07 eV (or 295.8 kJ/mol) the bond strength between Cs-O, which was obtained from Ref. 63
-
- was replaced with the value of -3.07 eV (or 295.8 kJ/mol) the bond strength between Cs-O, which was obtained from Ref. 63.
-
-
-
-
68
-
-
0040590640
-
-
2 and the electron affinity for OH are obtained from Ref. 65. For a crude estimate of the electrostatic energy forming CsOH, Cs and OH are approximated as point charges separated by 3.29 Å, which is the weighted mean distance between Cs and O, reported in the x-ray diffraction study of CsOH by H. Jacobs et al. in Z. Naturforsch. 1981, 36b, 270. Then, the electrostatic energy of -4.38 eV was further corrected for the repulsive contribution, which was assumed to be 10%, to yield the value of -3.94 eV.
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Jacobs, H.1
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69
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-
85034494709
-
-
The calculated values are obtained after correcting the readjustment of the Fermi level
-
The calculated values are obtained after correcting the readjustment of the Fermi level.
-
-
-
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