Three-dimensional cage-like polycyanopolycadmate network accommodating Werner complexes; the crystal structure of [Cd(dien)2]·[Cd2(CN)3(dien) 2]·[Cd8(CN)19]·3H2O (dien = (H2N(CH2)2)2NH, diethylenetriamine)

Chemistry Letters

Volumn , Issue 1, 1997, Pages 61-62

  Kurihara, Hiroyuki ^a   Nishikiori, Shin Ichi ^a   Iwamoto, Toschitake ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0005482753     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1997.61     Document Type: Article

References (17)

1. a) C.-H. Kim, T. Soma, S. Nishikiori, and T. Iwamoto. Chem. Lett., 1996, 89;
2. b) B. F. Abrahams, B. F. Hoskins, J. Liu, and R. Robson, J. Am. Chem Soc., 113, 3045 (1991); B. F. Abrahams, M. J. Hardie, B. F. Hoskins, R. Robson, and E. E. Sutherland, J. Chem. Soc., Chem Commun., 1994, 1049;
3. b) B. F. Abrahams, B. F. Hoskins, J. Liu, and R. Robson, J. Am. Chem Soc., 113, 3045 (1991); B. F. Abrahams, M. J. Hardie, B. F. Hoskins, R. Robson, and E. E. Sutherland, J. Chem. Soc., Chem Commun., 1994, 1049;
4. c) J. Kim, D. Whang, J. I. Lee, and K. Kim, J. Chem. Soc., Chem. Commun., 1993, 1400; J. Kim, D. Whang, Y-S. Koh, and K. Kim, J. Chem. Soc., Chem Commun, 1994, 637.
5. c) J. Kim, D. Whang, J. I. Lee, and K. Kim, J. Chem. Soc., Chem. Commun., 1993, 1400; J. Kim, D. Whang, Y-S. Koh, and K. Kim, J. Chem. Soc., Chem Commun, 1994, 637.
6. K.-M. Park, M. Hashimoto, T. Kitazawa, and T. Iwamoto, Chem. Lett., 1990, 1701; H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992); H. Yuge and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1993. 2841; T. Kitazawa, S. Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695; T. Iwamoto, S. Nishikiori, and T. Kitazawa, Supramolec. Chem., 6. 179.(1995); T. Iwamoto, J. Incl. Phenom., 24, 61 (1996).
7. K.-M. Park, M. Hashimoto, T. Kitazawa, and T. Iwamoto, Chem. Lett., 1990, 1701; H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992); H. Yuge and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1993. 2841; T. Kitazawa, S. Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695; T. Iwamoto, S. Nishikiori, and T. Kitazawa, Supramolec. Chem., 6. 179.(1995); T. Iwamoto, J. Incl. Phenom., 24, 61 (1996).
8. K.-M. Park, M. Hashimoto, T. Kitazawa, and T. Iwamoto, Chem. Lett., 1990, 1701; H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992); H. Yuge and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1993. 2841; T. Kitazawa, S. Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695; T. Iwamoto, S. Nishikiori, and T. Kitazawa, Supramolec. Chem., 6. 179.(1995); T. Iwamoto, J. Incl. Phenom., 24, 61 (1996).
9. K.-M. Park, M. Hashimoto, T. Kitazawa, and T. Iwamoto, Chem. Lett., 1990, 1701; H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992); H. Yuge and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1993. 2841; T. Kitazawa, S. Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695; T. Iwamoto, S. Nishikiori, and T. Kitazawa, Supramolec. Chem., 6. 179.(1995); T. Iwamoto, J. Incl. Phenom., 24, 61 (1996).
10. K.-M. Park, M. Hashimoto, T. Kitazawa, and T. Iwamoto, Chem. Lett., 1990, 1701; H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992); H. Yuge and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1993. 2841; T. Kitazawa, S. Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695; T. Iwamoto, S. Nishikiori, and T. Kitazawa, Supramolec. Chem., 6. 179.(1995); T. Iwamoto, J. Incl. Phenom., 24, 61 (1996).
11. K.-M. Park, M. Hashimoto, T. Kitazawa, and T. Iwamoto, Chem. Lett., 1990, 1701; H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992); H. Yuge and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1993. 2841; T. Kitazawa, S. Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695; T. Iwamoto, S. Nishikiori, and T. Kitazawa, Supramolec. Chem., 6. 179.(1995); T. Iwamoto, J. Incl. Phenom., 24, 61 (1996).
12. 3: C, 20.06; H, 2.57; N, 20.93%.
13. 5 A difficulty of discrimination between C and N of cyanide bridges appeared in the refinement process. There are twelve crystallographically independent cyanide ligands in the crystal. The atoms of eight cyanide ligands were assigned from bond distances between Cd and the coordinating atom, but the atoms of two cyanide ligands were not. Another two cyanide ligands are in a structural disordered state caused by the space group. Each atom of the last four cyanide ligands was treated as a hybrid atom which consists of a 50% C atom and a 50% N atom.
14. G. M. Sheldrick, SHELXS 86, Program for Crystal Structure Determination, University of Göttingen, 1986; G. M. Sheldrick, SHELXL 93, Program for Crystal Structure Determination, University of Göttingen, 1993.
15. G. M. Sheldrick, SHELXS 86, Program for Crystal Structure Determination, University of Göttingen, 1986; G. M. Sheldrick, SHELXL 93, Program for Crystal Structure Determination, University of Göttingen, 1993.
16. G. O. Morpurgo, V. Mosini, P. Porta, G. Dessy, and V. Fares, J. Chem. Soc. Dalton, 1980, 1272; G. O. Morpurgo. ,V. Mosini, P. Porta, G. Dessy, and V. Fares, J. Chem. Soc. Dalton, 1981, 111.
17. G. O. Morpurgo, V. Mosini, P. Porta, G. Dessy, and V. Fares, J. Chem. Soc. Dalton, 1980, 1272; G. O. Morpurgo. ,V. Mosini, P. Porta, G. Dessy, and V. Fares, J. Chem. Soc. Dalton, 1981, 111.