A novel three-dimensional cyano-linked metal-complex host clathrate [{Cd(imH)}{Cd(CN)3(imH)}{Cd(CN)3}]·C 6H6 (imH = imidazole): X-ray single crystal structure and solid state113Cd and2H NMR

Chemistry Letters

Volumn , Issue 1, 1996, Pages 89-90

  Kim, Chong Hyeak ^a   Soma, Takayoshi ^a   Nishikiori, Shin Ichi ^a   Iwamoto, Toschitake ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20544436875     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.89     Document Type: Article

References (11)

1. a) T. Kitazawa, S. Nishikiori, R. Kuroda, and T. Iwamoto, Chem. Lett., 1988, 459;
2. J. Chem. Soc., Dalton Trans., 1994, 1029;
3. b) T. Kitazawa, S, Nishikiori, and T. Iwamoto, J. Chem. Soc., Dalton Trans., 1994, 3695;
4. c) T. Kitazawa, T. Kikuyama, M. Takahashi, and M. Takeda, J. Chem. Soc., Dalton Trans., 1994, 2933.
5. 3 GOF = 1.45. Details of the crystal structure determination will be reported elsewhere along with those for the analogous clathrates.
6. G. M. Sheldrick, SHELX 76, Program for crystal structure determinations. University of Cambridge, 1976.
7. The atomic notations Cd(o), Cd(t1) and Cd(t2) have been applied for those given by symmetry operations.
8. 2O external standard; b) 46.09 MHz Larmor frequency, quadrupole echo pulse sequence with 2μs 90° pulse width and 35 μs pulse spacing time and 4 s recycle delay time, at 297, 323, 348, 373, and 398 K.
9. S. Nishikiori, C. I. Ratcliffe, and J. A. Ripmeester, Can. J. Chem., 68, 2270 (1990);
10. J. Am. Chem. Soc., 114, 8590 (1992).
11. S. Nishikiori, C. I. Ratcliffe, and J. A. Ripmeester, J. Phys. Chem., 95, 1589 (1991).