Synthesis of (η5-cyclopentadienyl)(η 4-cyclopenta-2,4-dien-1-thione)cobalt by the reaction of cobaltacyclopentadiene derivative with CS2 in the presence of Co(I) complex

Chemistry Letters

Volumn , Issue 2, 1998, Pages 121-122

  Lee, Jong Chan ^a   Tomita, Ikuyoshi ^a   Endo, Takeshi ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0005347180     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1998.121     Document Type: Article

References (23)

1. a) J. D. Gilbert, M. C. Braid, and G. Wilkinson, J. Chem. Soc. (A), 1968, 2198.
2. b) G. R. Clark, K. R. Grudy, R. O. Harris, S. M. James, and W. P. Roper, J. Organomet. Chem., 90, C37 (1975).
3. c) T. J. Collins and W. P. Roper, J. Organomet. Chem., 139, C9 (1977).
4. d) T. J. Collins and W. P. Roper, J. Organomet. Chem., 139, C56 (1977).
5. e) H. Werner and K. Leonhard, Angew. Chem., Int. Ed., 18, 627 (1979).
6. f) J. Fortune and A. R. Manning, J. Organomet. Chem., 190, C95 (1980).
7. G. P. Elliott, W. R. Roper, and J. M. Waters, J. Chem. Soc., Chem. Commun., 1982, 811.
8. J. Campora, E. Carmona, E. Gutierrez-Puebla, M. L. Poveda, and C. Ruiz, Organomet. 7, 2577 (1988).
9. 2 to give dithiolactone derivatives has been reported. See, Y. Wakatsuki and H. Yamazaki, J. Chem. Soc., Chem. Commun., 1973, 280. By the same group, related reactions of the cobaltacyclopentadienes with nitriles, isocyanates, sulfur, etc. have been also reported. See, a) P. Hong and H. Yamazaki, Synthesis, 1977, 50.
10. 2 to give dithiolactone derivatives has been reported. See, Y. Wakatsuki and H. Yamazaki, J. Chem. Soc., Chem. Commun., 1973, 280. By the same group, related reactions of the cobaltacyclopentadienes with nitriles, isocyanates, sulfur, etc. have been also reported. See, a) P. Hong and H. Yamazaki, Synthesis, 1977, 50.
11. b) Y. Wakatsuki and H. Yamazaki, J. Chem. Soc., Dalton Trans., 1978, 1278.
12. c) H. Yamazaki and Y. Wakatsuki, J. Organomet. Chem., 139, 157 (1977).
13. d) Y. Wakatsuki and H. Yamazaki, J. Organomet. Chem., 139, 169 (1977).
14. e) F. W. Grevels, Y. Wakatsuki, and H. Yamazaki, J. Organomet. Chem., 141, 331 (1977).
15. f) Y. Wakatsuki and H. Yamazaki, J. Organomet. Chem., 149, 385 (1978).
16. g) H. Yamazaki and Y. Wakatsuki, Bull. Chem. Soc. Jpn., 52, 1239 (1979).
17. h) K. Yasufuku, A. Hamada, K. Aoki, and H. Yamazaki, J. Am. Chem. Soc., 102, 4363 (1980).
18. i) Y. Wakatsuki, H. Yamazaki, and H. Iwasaki, J. Am. Chem. Soc., 95, 5781 (1973).
19. j) P. Hong and H. Yamazaki, Tetrahedron Lett., 15, 1333 (1977).
20. 25CoS: C, 77.85; H, 4.80%.
21. 4-cyclopenta-2,4-dien-1-thione)ruthenium has been also observed at rather high field (161.82 ppm) that has been explained by the interaction with Ru atom on the neighboring molecule. See, M. Sato and M. Sensui, Chem. Lett., 1996, 991.
22. 28CoSI: C, 63.07; H, 4.23%.
23. ω = 0.087.