A novel oxidatively induced structural rearrangement of diruthenocenyl disulfide to the first transition-metal complex of 2,4-cyclopentadien-1-thione

Chemistry Letters

Volumn , Issue 11, 1996, Pages 991-992

  Sato, Masaru ^a   Sensui, Masa Aki ^a  

^a SAITAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030360755     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.991     Document Type: Article

References (16)

1. D. Astruc, "Electron Transfer and Radical Process in Transition-metal Chemistry," VCH Publishers, Inc., New York (1995).
2. For a recent example, see M. Sato, A. Kudo, Y. Kawata, and H. Saitoh, J. Chem. Soc., Chem. Commun., 1996, 25.
3. R. Schulz and A. Schweig, Angew. Chem., Int. Ed. Engl., 20, 570 (1981).
4. All new complexes had a satisfactory elemental analysis.
5. P. Shu, K. Bechgaard, and D. C. Cowan, J. Org. Chem., 41, 1849 (1976).
6. H. Fischer and R. Märkl, Chem. Ber., 115, 1349 (1982).
7. a) T. P. Smith, K. S. Kwan, H. Taube, A. Bino, and S. Cohen, Inorg. Chem., 23, 1943 (1984).
8. b) K. Kirchner, H. Taube, B. Scot, and R. D. Willett, Inorg. Chem., 32, 1430 (1993).
9. -1, T=298 K. 5688 measured reflections, 5055 unique reflections, 4224 reflections with I≥3σ(I) used in refinement, empirical absorption correction (ψ-scan), R=0.0377 and Rw=0.0456.
10. B. A. Karcher and R. A, Jacobson, J. Organomet. Chem., 132, 387 (1977).
11. S. Akabori, T. Kumagai, T. Shirashige, S. Sato, K. Kawazoe, C. Tamura, and M. Sato, Organometallics, 10, 2105 (1987). A similar feature was observed in ferrocene analogs.
12. a) L. S. Liebeskind and A. Bombrun, J. Am. Chem. Soc., 113, 8736 (1991).
13. b) K. Mauthner, C. Slugovc, K. Mereiter, R. Schmid, and K. Kirchner, Organometallics, 15, 181 (1996).
14. a) W. Reppe, H. Vetter, Justus Liebigs Ann. Chem., 582, 133 (1953).
15. b) M. L. H. Green, L. Pratt, and G. Wilkinson, J. Chem. Soc., 1960, 989.
16. The plane S(1)-C(1)-C(2)-C(5) is nearly planar, but the S(1)-C(1) bond is bent by 2.9° out of the plane C(1)-C(2)-C(5) toward the Ru atom.