Syntheses and reactions of some cluster complexes containing C4 ligands with iron, ruthenium and cobalt carbonyls

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 17, 2000, Pages 2939-2951

  Bruce, Michael I ^a   Low, Paul J ^a   Zaitseva, Natasha N ^a   Kahlal, Samia ^b   Halet, Jean Francois ^b   Skelton, Brian W ^c   White, Allan H ^c  

^a UNIVERSITY OF ADELAIDE   (Australia)

^b Laboratoire de Chimie du Solide et Inorganique Moleculaire de Rennes   (France)

^c UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0003103880     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b002406f     Document Type: Article

References (58)

1. P. Belanzoni, N. Re, A. Sgamellotti and C. Floriani, J. Client. Soc., Dalton Trans., 1998, 1825, and references cited therein.
2. P. Belanzoni, N. Re, M. Rosi, A. Sgamellotti and C. Floriani, Organometallics, 1996, 15, 4264;
3. P. Belanzoni, N. Re, A. Sgamellotti and C. Floriani, J. Chem. Soc., Dalton Trans., 1997, 4773.
4. Y. Zhou, J. W. Seyler, W. Wene, A. M. Arif and J. A. Gladysz, J. Am. Chem. Soc., 1993, 115, 8509;
5. J. W. Seyler, W. Weng, Y. Zhou and J. A. Gladysz, Organomelallics, 1993, 12, 3802.
6. N. Le Narvorand C. Lapinte, J. Chem. Soc.. Chem. Commun., 1993, 357;
7. N. Le Narvor, L. Toupet and C. Lapinte, J. Am. Chem. Soc., 1995, 117, 7129.
8. M. Brady, W. Weng and J. A. Gladysz, J. Chem. Soc., Chem. Commun., 1994, 2655;
9. T. Bartik, B. Bartik, M. Brady, R. Dembinsky and J. A. Gladysz, Ange Chem., 1996, 108, 467;
10. Angew. Chem., Im. Ed. Engt., 1996, 35, 414;
11. B. Bartik, R. Dembinski, T. Bartik, A. M. Arif and J. A. Gladysz, New J. Chem., 1997, 21, 739.
12. F. Coat and C. Lapinte, Organometallics, 1996, 15, 477.
13. B. H. Robinson and J. L. Spencer, J. Organomet. Chem., 1971, 30, 267;
14. R. J. Dellaca, B. R. Penfold, B. H. Robinson, W. T. Robinson and J. L. Spencer, Inorg. Chem., 1970, 9, 2204;
15. R. J. Dellaca and B. R. Penfold, Inorg. Chem., 1971, 10, 1269.
16. G. H. Worth, B. H. Robinson and J. Simpson, Organometallics, 1992, 11, 3863.
17. M. I. Bruce, J.-F. Halet, S. Kahlal, P. J. Low, B. W. Skelton and A. H. White, J. Organomet. Chem., 1999, 578, 155.
18. D. M. Norton, C. L. Stern and D. F. Shriver, Inorg. Chem., 1994, 33, 2701.
19. C. J. Adams, M. I. Bruce, E. Horn, B. W. Skelton, E. R. T. Tiekink and A. H. White, J. Chem. Soc., Dalton Trans., 1993, 3299.
20. S. B. Falloon, A. M. Arif and J. A. Gladysz, Chem. Commun., 1997, 629;
21. S. B. Falloon, S. Szafert, A. M. Arif and J. A. Gladysz, Chem. Eur. .7, 1998, 4, 1033.
22. M. I. Bruce, M. Ke, P. J. Low, B. W. Skelton and A. H. White, Organometallics, 1998, 17, 3539.
23. M. I. Bruce, B. W. Skelton, A. H. White and N. N. Zaitseva, J. Chem. Soc., Dalton Trans., 1996, 3151.
24. M. I. Bruce, P. A. Humphrey, E. Horn, E. R. T. Tiekink, B. W. Skelton and A. H. White, J. Organomet. Chem., 1992, 429, 207.
25. M. I. Bruce, N. N. Zaitseva, B. W. Skelton and A. H. White, J. Organomet. Chem., 1997, 536-537, 93.
26. G. Predieri, A. Tiripicchio, C. Vignali and E. Sappa, J. Organomet. Chem., 1988, 342, C33.
27. M. I. Bruce, P. J. Low, A. Werth, B. W. Skeiton and A. H. White, J. Chem. Soc., Dalton Trans., 1996, 1551.
28. V. A. Semion and Yu. T. Struchkov, Zh. Strukt. Khim., 1968, 9, 1046;
29. M.-C. Chen, Y.-J. Tsai, C.-T. Chen, Y.-C. Lin, T.-W. Tseng, G.-H. Lee and Y. Wang, Organometallics, 1991, 10, 378.
30. D. Braga, L. J. Farrugia, A. L. Gillon, F. Grepioni and E. Tedesco, Organometallics, 1996, 15, 4684.
31. M. I. Bruce, N. N. Zaitseva, B. W. Skelton and A. H. White, J. Cluster Sei., 1996, 7, 109.
32. M. I. Bruce, Client. Rev., 1991, 91, 197 and references therein.
33. E. Roland, W. Bernhardt and H. Vahrenkamp, Chem. Ber., 1985 118, 2858.
34. 24 Model 9 was optimized with the aid of DF calculations under the C2h symmetry constraint in order to reduce computational effort. The following distances (A) and bond angles (°) were obtained: Ru(l)-Ru(2-3) 2.794; Ru(2)-Ru(3) 2.750; Ru(l)-C(l) 1.993; Ru(2, 3)-C(l) 2.220; Ru(2, 3)-C(2) 2.245; C(1)-C(2) 1.314; C(2)-C(3) 1.374; Ru-C(O) (av.) 1.913; C-O (av.) 1.178; C(i)-C(2)-C(3) 152.5. A HOMO/LUMO gap of 2.47 eV was computed.
35. There are different ways to count electrons formally in the tetracarbon moiety. We choose here to consider C4 as a dianionic species rather than a neutral species in order that it agrees with the octet rule. Note that the number of frontier molecular orbitals of C4 which may participate to the M-C bonding is independent of the electron-counting convention.
36. B. E. R. Schilling and R. Hoffmann, J. Am. Cliem. Soc., 1979, 101, 3456.
37. J.-F. Halet and D. M. P. Mingos, Organomelallics, 1988, 7, 51;
38. G. Frapper and J.-F. Halet, Organometallics, 1995, 14, 5044;
39. G. Frapper, J.-F. Halet and M. I. Bruce, Organometallics, 1997, 16, 2590.
40. M. J. McGIinchey, in Topics in Physical Organometallic Chemistry, ed. M. Gielen, Freund Publishing House, London, 1992, vol. 4, p. 41.
41. M. I. Bruce, N. N. Zaitseva, B. W. Skelton and A. H. White, 7rv. Akad. Nauk, Ser. Kliim., 1998, 1012;
42. Russ. Client. Bull., 1998, 47, 983.
43. M.-C. Chung, A. Sakurai, M. Akita and Y. Moro-oka, Organometallics, 1999, 18, 4684.
44. H. Vahrenkamp, Ad\: Organomet. Cliem., 1983, 22, 169;
45. R. D. Adams, in Comprehensive Orgunometatlic Chemistry II, eds. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1995, vol. l.ch. l.pp. 1-22.
46. M. I. Bruce, N. N. Zaitseva, B. W. Skelton and A. H. White, Polyhedron, 1995, 14, 2647.
47. W. Henderson, J. S. Mclndoe, B. K. Nicholson and P. J. Dyson, J. Chem. Soc., Dation Trans., 1998, 519.
48. S. R. Hall, G. S. D. King and J. M. Stewart (Editors), The XTAL 3.4 Users' Manual, University of Western Australia, Lamb, Perth, 1994.
49. Amsterdam Density Functional (ADF) Program, release 2.0.1, Vrije Universteit, Amsterdam, 1996.
50. (a) E. J. Baerends, D. E. Ellis and P. Ros, Chem. Phys., 1973, 2, 41;
51. (b) E. J. Baerends and P. Ros, Int. J. Quantum Chem., 1978, S12, 169;
52. P. M. Boerrigter, G. te Velde and E. J. Baerends, Int. J. Quantum Chem., 1988, 33", 87;
53. (
54. S. D. Vosko, L. Wilk and M. Nusair, Can. J. Chem., 1990, 58, 1200.
55. L. Verluis and T. Ziegler, J. Chem. Phys., 1988, 322, 88.
56. R. Hoffmann, J. Chem. Phys., 1963, 39, 1397;
57. R. Hoffmann and W. N. Lipscomb, J. Chem. Phys., 1962, 36, 2179.
58. C. Mealli and D. Proserpio, J. Chem. Edite., 1990, 67, 399.