Experimental determination of aqueous sodium-acetate dissociation constants at temperatures from 20 to 240°C

Chemical Geology

Volumn 151, Issue 1-4, 1998, Pages 69-84

  Fournier, Patricia ^a   Oelkers, Eric H ^a   Gout, Robert ^a   Pokrovski, Gleb ^a  

^a CNRS   (France)

Author keywords

Aqueous complex formation; Dissociation constants; Hydrothermal solutions; Sodium acetate

Indexed keywords

EID: 0002914577     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0009-2541(98)00071-0     Document Type: Article

References (45)

1. Akitt, J.W., Farnsworth, J.A., 1985. Nuclear magnetic resonance and molar-volume studies of the complex formed between aluminum(III) and the sulfate anion. Chem. Soc. Faraday Trans. I., pp. 193-205.
2. Alcock, N.W., Tracy, V.M., Waddington, T.C., 1976. Acetates and acetato complexes: Part 2. Spectroscopic studies. J. Chem. Soc. Dalton Trans. 21, 2243-2249.
3. Archer, D.W., Monk, C.B., 1964. Ion-association constants of some acetates by pH (glass electrode) measurements. J. Chem. Soc., pp. 3117-3122.
4. Barnes, J.C., 1964. Stability constants and spectra of some lanthanide complexes. J. Chem. Soc. 78, 3880-3885.
5. Bates, R.G., 1973. Determination of pH. Wiley-Interscience, 479 pp.
6. Bénézeth, P., Castet, S., Dandurand, J.L., Gout, R., Schott, J., 1994. Experimental study of aluminum acetate complexing between 60 and 200°C. Geochim. Cosmochim. Acta 58, 4561-4571.
7. Carothers, W.W., Kharaka, Y.K., 1978. Aliphatic acid anions in oil-field waters - implications for origin of natural gas. Am. Assoc. Pet. Geol. Bull. 62, 2441-2453.
8. Castet, S., Dandurand, J.L., Schott, J., Gout, R., 1993. Boehmite solubility and aqueous speciation in hydrothermal solutions (90-350°C): Experimental study and modeling. Geochim. Cosmochim. Acta 57, 4869-4884.
9. Choppin, G.R., Graffeo, A.J., 1965. Complexes of trivalent lanthanide and actinide ions II. Inner-sphere complexes. Inorganic Chemistry 4, 1254-1257.
10. Choppin, G.R., Rizkalla, E.N., 1994. Solution chemistry of actinides and lanthanides In: Gscheunder et al. (Eds.), Handbook on the Physics and Chemistry of Rare Earths Vol. 18 - Lanthanides/Actinides Chemistry, pp. 559-590.
11. Couturier, Y., Michard, G., Sarazin, G., 1984. Constants de formation des complex es hydroxydes de l'aluminium en solution aqueuse de 20 à 70°C. Geochim. Cosmochim. Acta 48, 649-659.
12. 2+ complexes of low molecular weight ligands in aqueous solution. J. Chem. Soc. Dalton, pp. 2353-2361.
13. Davis, A.R., Oliver, B.C., 1973. Raman spectroscopic evidence for contact ion paring in aqueous magnesium sulfate solutions. J. Phys. Chem. 77, 1315-1316.
14. Fein, J.B., 1991a. Experimental study of aluminum-, calcium-, and magnesium-acetate complexing at 80°C. Geochim. Cosmochim. Acta 55, 955-964.
15. Fein, J.B., 1991b. Experimental study of aluminum oxalate complexing at 80°C: Implications for the formation of secondary porosity within sedimentary reservoirs. Geology 19, 1037-1040.
16. Fein, J.B., 1994. Porosity enhancement during clastic diagenesis as a result of aqueous metal-carboxylate complexation: Experimental studies. Chem. Geol. 115, 263-279.
17. Fein, J.B., Hestrin, J.E., 1994. Experimental studies of oxalate complexation at 80°C: Gibbsite, amorphous silica, and quartz solubilities in oxalate-bearing fluids. Geochim. Cosmochim. Acta 58, 4817-4829.
18. Fournier, P., Oelkers, E.H., Gout, R.A., 1997. A Raman spectroscopic study of lead acetate complex formation at temperatures from 25 to 240°C. Terra Abstracts, 9:Abstracts Supplement No. 1, p. 567.
19. 4) solubility in acetate solutions: Determination of stability constants for lead acetate complexes to 85°C. Geochim. Cosmochim. Acta 53, 359-366.
20. Helgeson, H.C., Kirkham, D.H., Flowers, G.C., 1981. Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures IV. Calculation of activity coefficients, osmotic coefficients and apparent molal and standard and partial molal properties to 600°C and 5 kb. Am. J. Sci. 281, 1249-1516.
21. Johnson, J.W., Oelkers, E.H., Helgeson, H.C., 1992. SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bars and 0° to 1000deg;C. Computers and Geoscience 18, 889-947.
22. Larsson, R., 1964. Studies on metal complexes in aqueous solution by infrared spectroscopy: IV. An indication of the existence of outer sphere complexes in some sulfate systems. Acta. Chem. Scand. 18, 1923-1936.
23. Mac Gowan, D.B., Surdam, R.C., 1988. Difunctional carboxylic acids anions in oilfield waters. Org. Geochem. 12, 245-259.
24. Oelkers, E.H., Helgeson, H.C., 1989. Calculation of the transport properties of aqueous species at pressures to 5 KB and temperatures to 1000°C. J. Soln. Chem. 18, 601-640.
25. Oelkers, E.H., Helgeson, H.C., 1990. Triple ion anions and polynuclear complexing in supercritical electrolyte solutions. Geochim. Cosmochim. Acta 54, 727-738.
26. - in aqueous solution from 275 to 320°C. J. Soln. Chem. 17, 865-885.
27. Ng, J.B., Shurvell, H.F., 1985. A study of the self-association of acetic acid in aqueous solution using Raman spectroscopy. Can. J. Spectrosc. 30(6), 149-153.
28. Ng, J.B., Shurvell, H.F., 1987. Application of factor analysis and band contour resolution technique to the Raman spectra of acetic acid in aqueous solution. J. Phys. Chem. 91, 496-500.
29. Palmer, D.A., Drummond, S.E., 1988. Potentiometric determination of the molal formation constants of ferrous acetate complexes in aqueous solutions to high temperatures. J. Phys. Chem. 92, 6795-6800.
30. 4 in hydrothermal solutions using a new high temperature sodium selective glass electrode. Implications for boron isotope fractionation. Chem. Geol. 124, 253-265.
31. Pokrovski, G., Gout, R., Schott, J., Zotov, A., Harrichoury, J.-C., 1996a. Thermodynamic properties and stoichiometry of As(III) hydroxide complexes at hydrothermal conditions. Geochim. Cosmochim. Acta 60, 737-739.
32. Pokrovski, G.S., Schott, J., Harrichoury, J.-C., Sergeyev, A.S., 1996b. The stability of aluminum silicate complexes in acidic solutions from 25 to 150°C. Geochim. Cosmochim. Acta 60, 2495-2501.
33. Posey, F.A., Taube, H., 1956. The outer sphere association of sulfate ion with tripositice cobaltammine ions. J. Am. Chem. Soc. 78, 15-20.
34. Roux, J., Beny, C., 1989. Exploitation informatique des données obtenues par spectrométrie Raman. Géoraman - 89 Contributions, 21.
35. Ruaya, J.R., Seward, T.M., 1987. The ion-pair constant and other properties of HCI up to 350°C. Geochim. Cosmochim. Acta 51, 121-130.
36. Semmler, J., Irish, D.E., 1988. Vibrational spectral studies of solutions at elevated temperatures and pressures: IX. Acetic acid. J. Sol. Chem. 17, 805-825.
37. Semmler, J., Irish, D.E., Ozeki, I., 1990. Vibrational spectral studies of solutions at elevated temperatures and pressures: 12. Magnesium acetate. Geochim. Cosmochim. Acta 54, 947-954.
38. Shock, E.L., 1995. Organic acids in hydrothermal solutions: Standard molal thermodynamic properties of carboxylic acids and estimates of dissociation constants at high temperatures and pressures. Am. J. Sci. 295, 496-580.
39. Shock, E.L., Koretsky, C.M., 1993. Metal-organic complexes in geochemical processes: Calculation of standard partial molal thermodynamic properties of aqueous acetate complexes at high pressures and temperatures. Geochim. Cosmochim. Acta 57, 4899-4922.
40. Shock, E.L., Oelkers, E.H., Johnson, J.W., Sverjensky, D.A., Helgeson, H.C., 1992. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures Effective electrostatic radii, dissociation constants and the standard molal properties to 1000°C and 5 kbar. J. Chem. Soc. Faraday Trans. 88, 803-826.
41. 27Al nuclear magnetic resonance study of speciation and equilibria in the aluminum(III)-oxalic acid-hydroxide system. J. Chem. Soc. Dalton Trans., pp. 2665-2669.
42. Spinner, E., 1964. The vibration spectra of some substituted acetate ions. J. Chem. Soc. 812, 4217-4226.
43. Thyne, G.D., Harrison, W.J., Alloway, M.D., 1992. Experimental study of the stability of the Al-oxalate complexation at 100°C and calculations of the effects of complexation on clastic diagenesis In: Kharaka, Y., Maest, A. (Eds), Water-Rock Interaction. Balkema, Rotterdam, pp. 353-357.
44. Yang, M.M., Crerar, D.A., Irish, D.E., 1989. Raman spectroscopic study of lead and zinc acetate complexes in hydrothermal solutions. Geochim. Cosmochim. Acta 53, 319-326.
45. Wolery, T.J., 1979. Calculation of chemical equilibrium between aqueous solutions and minerals the EQ3/6 software package. Lawrence Livermore National Laboratory, Livermore, California, UCRL-52658.