Syntheses, structures and properties of hydrosulfido-bridged diiridium and dirhodium complexes, [Cp*MCl(μ2-SH)2MCp *Cl] and [Cp*M(μ2-SH)3MCp*] + (M=Ir, Rh; Cp*=η5-C5Me5)

Inorganica Chimica Acta

Volumn 267, Issue 1, 1998, Pages 73-79

  Tang, Zhen ^a   Nomura, Yasuo ^a   Ishii, Youichi ^a   Mizobe, Yasushi ^a,b   Hidai, Masanobu ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

Author keywords

Crystal structures; Dinuclear complexes; Hydrosulfido bridged complexes; Iridium complexes; Rhodium complexes

Indexed keywords

CRYSTAL STRUCTURE; HYDROGEN BONDS; ISOMERS; LIGANDS; RHODIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

ANTI ISOMERS; CONTINUOUS STIRRINGS; DINUCLEAR COMPLEX; DIRHODIUM COMPLEX; HYDROSULFIDO-BRIDGED COMPLEXES; IRIDIUM COMPLEX; RHODIUM COMPLEXES; STRUCTURES AND PROPERTIES;

IRIDIUM COMPOUNDS;

EID: 0002845220     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0020-1693(97)05554-0     Document Type: Article

References (46)

1. (a) T. Saito, in M.H. Chisholm (ed.), Early Transition Metal Clusters with π-Donor Ligands, VCH, New York, 1995, Ch. 3;
2. (b) I. Dance and K. Fisher, Prog. Inorg. Chem., 41 (1994) 637;
3. (c) T. Shibahara, Coord. Chem. Rev., 123 (1993) 73;
4. (d) B. Krebs and G. Henkel, Angew. Chem., Int. Ed. Engl., 30 (1991) 769;
5. (e) R.H. Holm, S. Ciurli and J.A. Weigel, Prog. Inorg. Chem., 38 (1990) 1.
6. (a) C. Bianchini and A. Meli, J. Chem. Soc., Dalton Trans., (1996) 801;
7. (b) V. Riaz, O.J. Curnow and M.D. Curtis, J. Am. Chem. Soc., 116 (1994) 4357;
8. (c) B.C. Wiegand and C.M. Friend, Chem. Rev., 92 (1992) 491;
9. (d) J. Chen, L.M. Daniels and R.J. Angelici, J. Am. Chem. Soc., 112 (1990) 199;
10. (a) R.J. Angelici, Acc. Chem. Res., 21 (1988) 387.
11. (a) D.C. Rees, M.K. Chan and J. Kim, Adv. Inorg. Chem., 40 (1994) 89;
12. (b) D. Coucouvanis, in E.I. Stiefel, D. Coucouvanis and W.E. Newton (eds.), Molybdenum Enzymes, Cofactors, and Model Systems, American Chemical Society, Washington, DC, 1993, p. 304;
13. (c) Adv. Inorg. Chem., 38 (1992).
14. (a) T. Murata, Y. Mizobe, H. Gao, Y. Ishii, T. Wakabayashi, F. Nakano, T. Tanase, S. Yano, M. Hidai, I. Echizen, H. Nanikawa and S. Motomura, J. Am. Chem. Soc., 116 (1994) 3389;
15. (b) T. Wakabayashi, Y. Ishii, T. Murata, Y. Mizobe and M. Hidai, Tetrahedron. Lett., 36 (1995) 5585;
16. (c) T. Wakabayashi, Y. Ishii, K. Ishikawa and M. Hidai, Angew. Chem., Int. Ed. Engl., 35 (1996) 2132;
17. (d) M. Rakowski Dubois, Chem. Rev., 89 (1989) 1.
18. (a) M. Hidai, Y. Mizobe and H. Matsuzaka, J. Organomet. Chem., 473 (1994) 1, and Refs. therein;
19. (b) M. Nishio, H. Matsuzaka, Y. Mizobe and M. Hidai, Organometallics, 14 (1995) 965;
20. (c) H. Matsuzaka, Y. Takagi, Y. Ishii, M. Nishio and M. Hidai, Organometallics, 14 (1995) 2153;
21. (d) K. Hashizume, Y. Mizobe and M. Hidai, Organometallics, 14 (1995) 5367;
22. (e) Y. Mizobe, M. Hosomizu, Y. Kubota and M. Hidai, J. Organomet. Chem., 507 (1996) 179;
23. (f) M. Nishio, H. Matsuzaka, Y. Mizobe and M. Hidai, Angew. Chem., Int. Ed. Engl., 35 (1996) 872;
24. (g) J. Qü, H. Matsuzaka, Y. Ishii and M. Hidai, Chem. Lett., (1996) 767;
25. (h) H. Matsuzaka, J. Qü, T. Ogino, M. Nishio, Y. Nishibayashi. Y. Ishii, S. Uemura and M. Hidai, J. Chem. Soc., Dalton Trans., (1996) 4307.
26. K. Hashizume, Y. Mizobe and M. Hidai, Organometallics, 15 (1996) 3303.
27. Z. Tang, Y. Nomura, Y. Ishii, Y. Mizobe and M. Hidai, Organometallics, 16 (1997) 151.
28. R.N. Grimes, Inorg. Synth., 29 (1992) 229.
29. TeXsan, crystal structure analysis package, Molecular Structure Corp., The Woodlands, TX, 1985 and 1992.
30. P.T. Beurskens, G. Admiraal, G. Beurskens, W.P. Bosman, S. Garcia-Granda, R.O. Gould, J.M.M. Smits and C. Smykalla, PATTY, The DIRDlF Program System, Tech. Rep., Crystallography Laboratory, University of Nijmegen, Nijmegen, Netherlands, 1992.
31. A.M. Mueting, P. Boyle and L.H. Pignolet, Inorg. Chem., 23 (1984) 44.
32. C. Bianchini, C. Mealli, A. Meli and M. Sabat, Inorg. Chem., 25 (1986) 4618.
33. A.M. Mueting, P.D. Boyle, R. Wagner and L.H. Pignolet, Inorg. Chem., 27 (1988) 271.
34. (a) D. Galli, L. Garlaschelli, G. Ciani, A. Fumagalli, S. Martinengo and A. Sironi, J. Chem. Soc., Dalton Trans., (1984) 55;
35. (b) R. Della Pergola, L. Garlaschelli, S. Martinengo, F. Demartin, M. Manassero and M. Sansoni, J. Chem. Soc., Dalton Trans., (1986) 2463;
36. (c) S.T. Mckenna and E.L. Muetterties, Inorg. Chem., 26 (1987) 1296;
37. (d) T.A. Bright. R.A. Jones, S.U. Koschmieder and C.M. Nunn, Inorg. Chem., 27 (1988) 3819;
38. (e) A.M. Arif, J.G. Hefner, R.A. Jones and S.U. Koschmieder, Polyhedron, 7 (1988) 561;
39. (f) Y. Ozawa, A.V. Miguel and K. Isobe, J. Organomet. Chem., 433 (1992) 183;
40. (g) T. Nishioka and K. Isobe, Chem. Lett., (1994) 1661;
41. (h) A. Venturelli and T.B. Rauchfuss, J. Am. Chem. Soc., 116 (1994) 4824.
42. A. Nutton, P.M. Bailey and P.M. Maitlis, J. Chem. Soc., Dalton Trans., (1981) 1997.
43. (a) D.A. Dobbs and R.G. Bergman, J. Am. Chem. Soc., 114 (1992) 6908;
44. (b) Inorg. Chem., 33 (1994) 5329.
45. Q. Feng, H. Krautscheidd, T.B. Rauchfuss, A.E. Skaugset and A. Venturelli, Organometallics, 14 (1995) 297.
46. M. Herberhold, G.X. Jin and W. Millius, Chem. Ber., 128 (1995) 557.