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Volumn 28, Issue 9, 1987, Pages 985-988

Regio- and diastereoselectivity in aldol reactions of cyclopent-2-enone, 2-(5H)furanone and their derived trimethylsilyloxydienes

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EID: 0000074656     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)95893-3     Document Type: Article
Times cited : (61)

References (20)
  • 3
    • 84918482697 scopus 로고    scopus 로고
    • Yield refers to total diastereomers in the reaction as analysed by g.l.c., using internal standard. Isolated yield (medium pressure column chromatography) gave, typically, 30–50% of total separated diastereomers.
  • 4
    • 84918482696 scopus 로고    scopus 로고
    • For a related cyclopentanone study, see: J.E. Dubois and M. Dubois, J.C.S.Chem.Commun., 1968, 1567. For a review of transition states in aldol reactions see C.M. Heathcock, Asymmetric Synthesis, Vol.III, Academic Press, Orlando, Fl, 1983, 155.
  • 6
    • 49249150292 scopus 로고
    • Conveniently prepared from cyclopentenone (LDA, TMSCl, −78°), c.f. earlier Retro Diels Alder route
    • (1979) Tetrahedron Letters , pp. 3945
    • Bloch1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.