Direct Evidence of Solvent-Peroxovanadium Clusters by Electrospray Ionization Mass Spectrometry

European Journal of Inorganic Chemistry

Volumn , Issue 8, 1998, Pages 1193-1197

  Bortolini, Olga ^b   Conte, Valeria ^a   Di Furia, Fulvio ^a   Moro, Stefano ^a  

^a UNIVERSITY OF PADOVA   (Italy)

^b UNIVERSITY OF FERRARA   (Italy)

Author keywords

Ab initio calculations; Ion molecule reactions; Mass spectrometry; Peroxo complexes; Vanadium

Indexed keywords

COORDINATION REACTIONS; ELECTROSPRAY IONIZATION; MOLECULES; VANADIUM COMPOUNDS;

AB INITIO CALCULATIONS; DIRECT OBSERVATIONS; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; EXCHANGE REACTION; EXPERIMENTAL TECHNIQUES; ION MOLECULE/REACTION; METHANOL MOLECULES; PEROXOCOMPLEXES; SPECTROMETRY MEASUREMENTS; WATER MOLECULE;

MASS SPECTROMETRY;

EID: 0002389962     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0682(199808)1998:8<1193::AID-EJIC1193>3.0.CO;2-J     Document Type: Article

References (36)

1. [1a] V. Conte, F. Di Furia, S. Moro, J. Mol. Catal. 1995, 104, 159.
2. [1b] V. Conte, F. Di Furia, S. Moro, Inorg. Chim. Acta 1998, 272, 62.
3. O. W. Howarth, J. R. Hunt, J. Chem Soc., Dalton Trans. 1979, 1388. O. W. Howarth, A. T. Harrison, J. Chem. Soc, Dalton Trans. 1985, 1173. J. S. Jaswal, A. S. Tracey, Inorg. Chem. 1991, 30, 3718.
4. O. W. Howarth, J. R. Hunt, J. Chem Soc., Dalton Trans. 1979, 1388. O. W. Howarth, A. T. Harrison, J. Chem. Soc, Dalton Trans. 1985, 1173. J. S. Jaswal, A. S. Tracey, Inorg. Chem. 1991, 30, 3718.
5. O. W. Howarth, J. R. Hunt, J. Chem Soc., Dalton Trans. 1979, 1388. O. W. Howarth, A. T. Harrison, J. Chem. Soc, Dalton Trans. 1985, 1173. J. S. Jaswal, A. S. Tracey, Inorg. Chem. 1991, 30, 3718.
6. N. S. Campbell, A. C. Dengel, W. P. Griffith, Polyhedron 1989, 8, 1379.
7. V. Conte, F. Di Furia, S. Moro, S. Rabbolini, J Mol. Catal. 1996, 113, 175.
8. A. Bagno, V. Conte, F. Di Furia, S. Moro, J Phys. Chem. A 1997, 101, 4637.
9. H. Mimoun, The Chemistry of Peroxides (Ed.: S. Patai), Wiley, Chichester, U.K., 1983, chapter 15.
10. V. Conte, F. Di Furia, G. Modena, In Organic Peroxides (Ed.: W. Ando), Wiley, Chichester, U.K., 1992, .hapter 11.2.
11. C. M Whitehouse, R. N. Dreyer, M. Yamashita, J. B. Fenn, J. B. Anal. Chem. 1985, 57, 675.
12. J. B. Fenn, M. Mann, C. K. Meng, S. F. Wong, C. M. Whitehouse, Mass Spectrom. Rev. 1990, 10, 37.
13. R. Colton, A. D'Agostino, J. C. Traeger, Mass Spectrom. Rev. 1995, 14, 79.
14. Metal Ions in Biological Systems, vol. 31 ("Vanadium and its Role in Life") (Ed.: H Sigel), Marcel Dekker, Inc., New York, NY, 1995.
15. D. C. Crans, R. A. Felty, M.M. Miller, J. Am. Chem. Soc. 1991. 113, 265.
16. D. C. Crans, R. W. Marshman, M.S. Gottlieb, O. P. Anderson, M. M. Miller, Inorg. Chem. 1992, 31, 4939.
17. Dimeric vanadates in water solution are known species at higher pH values. See as an example: N. D. Chasteen, Vanadium in Biological Systems, Kluwer Academic Publishers, Dordrecht, 1990.
18. B. J.Hamstra G. J. Colpas, V. L. Pecoraro. Inorg. Chem. 1998, 37, 949.
19. K. D. Dobbs, W. J. Hehre, J. Comp. Chem. 1987, 8, 861.
20. A. D. Becke, J. Chem. Phys. 1993, 98, 5648.
21. P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 270.
22. Coordinate files for molecular models are available from the authors.
23. S. Favaro, L. Pandolfo, P. Traldi, Rapid Commun. Mass Spectrom. 1997, II, 1859.
24. T. Lover, W. Henderson, G. A Bowmaker, J. Seakins, R. P. Cooney, Inorg. Chem. 1997, 36, 3711. R. Colton, K. L. Harrison, Y. A. Mah, J. C. Traeger, Inorg. Chim. Acta 1995, 231, 65. R. Colton, B. D. James, I. D. Potter, J. C. Traeger, Inorg. Chem. 1993, 32, 2626.
25. T. Lover, W. Henderson, G. A Bowmaker, J. Seakins, R. P. Cooney, Inorg. Chem. 1997, 36, 3711. R. Colton, K. L. Harrison, Y. A. Mah, J. C. Traeger, Inorg. Chim. Acta 1995, 231, 65. R. Colton, B. D. James, I. D. Potter, J. C. Traeger, Inorg. Chem. 1993, 32, 2626.
26. T. Lover, W. Henderson, G. A Bowmaker, J. Seakins, R. P. Cooney, Inorg. Chem. 1997, 36, 3711. R. Colton, K. L. Harrison, Y. A. Mah, J. C. Traeger, Inorg. Chim. Acta 1995, 231, 65. R. Colton, B. D. James, I. D. Potter, J. C. Traeger, Inorg. Chem. 1993, 32, 2626.
27. R. Cooks, J. S. Patrick, T. Kotiaho, S. A. McLuckey, Mass Spectrom. Rev. 1994, 13, 287 and refs. cited therein.
28. J. W. Sam, X. J. Tang, J. Peisach, J. Am. Chem. Soc. 1994, 116, 5250. C. W. Fenwick, A. M. English, J. Am. Chem. Soc. 1996, 118, 12236. M. Bonchio, G. Licini, G. Modena, S. Moro, O. Bortolini, P. Traldi, W. A. Nugent, J. Chem. Soc., Chem. Commun. 1997, 869. D. Feichtinger, D. A. Plattner, Angew. Chem. 1997, 109, 1796; Angew. Chem. Int. Ed. Engl. 1997, 36, 1718.
29. J. W. Sam, X. J. Tang, J. Peisach, J. Am. Chem. Soc. 1994, 116, 5250. C. W. Fenwick, A. M. English, J. Am. Chem. Soc. 1996, 118, 12236. M. Bonchio, G. Licini, G. Modena, S. Moro, O. Bortolini, P. Traldi, W. A. Nugent, J. Chem. Soc., Chem. Commun. 1997, 869. D. Feichtinger, D. A. Plattner, Angew. Chem. 1997, 109, 1796; Angew. Chem. Int. Ed. Engl. 1997, 36, 1718.
30. J. W. Sam, X. J. Tang, J. Peisach, J. Am. Chem. Soc. 1994, 116, 5250. C. W. Fenwick, A. M. English, J. Am. Chem. Soc. 1996, 118, 12236. M. Bonchio, G. Licini, G. Modena, S. Moro, O. Bortolini, P. Traldi, W. A. Nugent, J. Chem. Soc., Chem. Commun. 1997, 869. D. Feichtinger, D. A. Plattner, Angew. Chem. 1997, 109, 1796; Angew. Chem. Int. Ed. Engl. 1997, 36, 1718.
31. J. W. Sam, X. J. Tang, J. Peisach, J. Am. Chem. Soc. 1994, 116, 5250. C. W. Fenwick, A. M. English, J. Am. Chem. Soc. 1996, 118, 12236. M. Bonchio, G. Licini, G. Modena, S. Moro, O. Bortolini, P. Traldi, W. A. Nugent, J. Chem. Soc., Chem. Commun. 1997, 869. D. Feichtinger, D. A. Plattner, Angew. Chem. 1997, 109, 1796; Angew. Chem. Int. Ed. Engl. 1997, 36, 1718.
32. J. W. Sam, X. J. Tang, J. Peisach, J. Am. Chem. Soc. 1994, 116, 5250. C. W. Fenwick, A. M. English, J. Am. Chem. Soc. 1996, 118, 12236. M. Bonchio, G. Licini, G. Modena, S. Moro, O. Bortolini, P. Traldi, W. A. Nugent, J. Chem. Soc., Chem. Commun. 1997, 869. D. Feichtinger, D. A. Plattner, Angew. Chem. 1997, 109, 1796; Angew. Chem. Int. Ed. Engl. 1997, 36, 1718.
33. Spartan, v. 4.0, Wavefunction, Inc., 18401 von Karman Ave. #370, Irvine, CA 92715, USA, 1995.
34. Gaussian 94, Revision C.2, M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, W. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M W. Wong, J. L. Andres, E. S. Replogle, R. Gomperts. R. L. Martin, D. J. Fox, J. S. Binkley, D. Defrees, J. J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzalez, J. A. Pople, Gaussian, Inc., Pittsburgh, 1995.
35. P. J. Hay, W.R. Wadt, J. Chem. Phys. 1985, 82, 299.
36. C. M. Breneman, K. B. Wiberg, J. Comp. Chem. 1990, 11, 361.