A mechanistic investigation of bromoperoxidases mimicking systems. Evidence of a hypobromite-like vanadium intermediate from experimental data and ab initio calculations

Journal of Molecular Catalysis A: Chemical

Volumn 113, Issue 1-2, 1996, Pages 175-184

  Conte, Valeria ^a   Di Furia, Fulvio ^a   Moro, Stefano ^a   Rabbolini, Susanna ^a  

^a UNIVERSITY OF PADOVA   (Italy)

Author keywords

Aromatics and olefins bromination; Bromoperoxidase; Hypobromite like vanadium complex; Peroxovanadium complex

Indexed keywords

EID: 0030601957     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1381-1169(96)00049-0     Document Type: Article

References (28)

1. [1] N.D. Chasteen (Ed.) Vanadium in Biological Systems, Kluwer Academic Publishers; Dordrecht, The Netherlands, 1990.
2. [2] H. Sigel and A. Sigel (Eds.) Metal Ions in Biological Systems, Vanadium and Its Role in Life, Vol. 31, Marcel Dekker, Inc. New York, 1995.
3. [3] N.D. Chasteen, Structure Bonding, 53 (1983) 104.
4. [4] B.R. Nechay, Annu. Rev. Toxicol., 24 (1984) 501.
5. [5] A. Butler, M.J. Claugue and G.E. Meister, Chem. Rev., 94 (1994) 625.
6. [6] R. Wever and B.E. Krenn, in Ref. 1, Chap. V, p. 81.
7. [7] A. Butler and C.J. Carrano, Coor. Chem. Rev., 109 (1991) 61.
8. [8] A. Butler and J.V. Walker, Chem. Rev., 93 (1993) 1937.
9. [9] P. Coughlin, S. Roberts, C. Rush and A. Willetts, Biotech. Lett., 15 (1993) 907.
10. [10] J. M. Arber, E. De Boer, C.D. Garner, S.S. Hasnian and R. Wever, Biochemistry, 28 (1989) 7968.
11. [11] F. Di Furia and G. Modena, Pure and Appl. Chem., 54 (1982) 1853.
12. [12] F. Di Furia and G. Modena, Rev. Chem. Interm., 6 (1985) 51.
13. [13] V. Conte, F. Di Furia and S. Moro, J. Mol. Cat., 94 (1994) 323.
14. [14] V. Conte, F. Di Furia and S. Moro, J. Mol. Cat., 104 (1995) 159.
15. [15] F. Secco, Inorg. Chem., 19 (1980) 2722.
16. [16] R.I. De La Rosa, M.J. Claugue and A. Butler, J. Am. Chem. Soc., 114 (1992) 760.
17. [17] R.C. Thompson, Inorg. Chem., 22 (1983) 584.
18. [18] V. Conte, F. Di Furia and G. Modena, in W. Ando (Ed.), Organic peroxides, 1992, Chap. 11.2, p. 559.
19. [19] V. Conte and F. Di Furia, in Catalytic Oxidations with Hydrogen Peroxide as Oxidant, G. Strukul (Ed.), Chapter 7, p. 223 Kluwer Academic Publishers, Dordrecht (1992).
20. [20] V. Conte, F. Di Furia and S. Moro, Tetrahedron Lett., 35 (1994) 7429.
21. [21] M. Andersson, V. Conte, F. Di Furia and S. Moro, Tetrahedron Lett., 36 (1995) 2675.
22. [22] V. Conte, F. Di Furia and S. Moro, Gazz. Chim. It., 125 (1995) 563.
23. [23] M. Bonchio, V. Conte, F. Di Furia, G. Modena, S. Moro and J.O. Edwards, Inorg. Chem., 33 (1994) 1631.
24. [24] M. Bonchio, V. Conte, F. Di Furia, G. Modena and S. Moro, J. Org. Chem., 21 (1994) 6262.
25. [25] K.D. Dobbs and W.J. Hehre, J. Comput. Chem., 8 (1987) 861.
26. [26] V. Conte, F. Di Furia and S. Moro, manuscript in preparation.
27. [27] A.D. Becke, J. Phys. Chem., 97 (1993) 9003.
28. [28] N.F. Dalleska, K. Honma, L.S. Sunderlin and P.B. Armentrout, J. Phys. Chem., 97 (1993) 596.