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26844501285
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note
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9b-d
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23
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note
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Racemic diol 2a has been prepared by acid hydrolysis of (d,l)-1a prepared as shown in Scheme 7. These results will be reported in the full paper.
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0030039872
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For a related work : Breitenbach, R.; Chiu, C. K. F. Massel, S. S.; Meltz, M.; Murtiashaw, C. W.; Pezzulo, S. L.; Staigers, T. Tetrahedron Asym. 1996, 7, 435.
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37
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6-7 double bond which leads in fact to the A-B ring of the steroid skeleton. This assistance could be precluded in 1a because substitution at the cyclopropyl carbon is usually a very unfavorable process. We are presently working towards this end.
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