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Volumn 17, Issue 20, 1998, Pages 4413-4416

Oxidation of metal carbynes in the presence of alkynes. Alkyne addition vs H-shift in the carbene intermediate

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Indexed keywords


EID: 0001712937     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980534x     Document Type: Article
Times cited : (9)

References (32)
  • 9
    • 85034288480 scopus 로고    scopus 로고
    • note
    • 2 = 1.108.
  • 14
  • 27
    • 85034304641 scopus 로고    scopus 로고
    • note
    • 14 If 1a were to initially protonate at the carbyne carbon to yield 3a, rearrangement of 3a to 4 would have to be faster than formation of 1-pentene from 3a under these conditions. This is highly unlikely since 4 has never been observed following generation of 3a under oxidative conditions.
  • 29
    • 0029791424 scopus 로고    scopus 로고
    • Protonations of metal complexes with unsaturated ligands can involve highly complex scenarios. See: Henderson, R. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 946-967.
    • (1996) Angew. Chem., Int. Ed. Engl. , vol.35 , pp. 946-967
    • Henderson, R.A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.