Synthesis of oriented inorganic-organic nanocomposite films from alkyltrialkoxysilane-tetraalkoxysilane mixtures

Journal of the American Chemical Society

Volumn 120, Issue 18, 1998, Pages 4528-4529

  Shimojima, Atsushi ^a   Sugahara, Yoshiyuki ^a   Kuroda, Kazuyuki ^a  

^a WASEDA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001681025     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja980236r     Document Type: Letter

References (27)

1. Judeinstein, P.; Sanchez, C. J. Mater. Chem. 1996, 6, 511.
2. Mann, S.; Burkett, S. L.; Davis, S. A.; Fowler, C. E.; Mendelson, N. H.; Sims, S. D.; Walsh, D.; Whilton, N. T. Chem. Mater. 1997, 9, 2300.
3. Brinker, C. J.; Scherrer, G. W. Sol-Gel Science; Academic Press: San Diego, CA, 1990.
4. Schmidt, H. J. Non-Cryst. Solids 1985, 73, 681.
5. Sakata, K.; Kunitake, T. J. Chem. Soc., Chem. Commun. 1990, 504.
6. Huo, Q.; Margolese, D. I.; Ciesla, U.; Demuth, D. G.; Feng, P.; Gier, T. E.; Sieger, P.; Firouzi, A.; Chmelka, B. F.; Schüth, F.; Stucky, G. D. Chem. Mater. 1994, 6, 1176.
7. (a) Ogawa, M. J. Am. Chem. Soc. 1994, 116, 7941.
8. (b) Ogawa, M. J. Chem. Soc., Chem. Commun. 1996, 1149.
9. Tanev, P. T.; Chibwe, M.; Pinnavaia, T. J. Nature 1994, 368, 321.
10. Raman, N. K.; Anderson, M. T.; Brinker, C. J. Chem. Mater 1996, 8, 1682.
11. Sjöblom, J.; Stakkestad, G.; Ebeltoft, H.; Friberg, S. E.; Claesson, P. Langmuir 1995, 11, 2652.
12. Lindén, M.; Slotte, J. P.; Rosenholm, J. B. Langmuir 1996, 12, 4449.
13. Sagiv, J. J. Am. Chem. Soc. 1980, 102, 92.
14. Ulman, A. An Introduction to Ultrathin Organic Films from Langmuir-Blodgett to Self-Assembly; Academic Press: New York, 1991; p 256.
15. Kessel, C. R.; Granick, S. Langmuir 1991, 7, 532.
16. Shimojima, A.; Sugahara, Y.; Kuroda, K. Bull. Chem. Soc. Jpn. 1997, 70, 2847.
17. Parikh, A. N.; Schivley, M. A.; Koo, E.; Seshadri, K.; Aurentz, D.; Mueller, K.; Allara, D. L. J. Am. Chem. Soc. 1997, 119, 3135.
18. 29Si MAS NMR, and FT-IR measurement.
19. m.
20. Glaser, R. H.; Wilkes, G. L.; Bronnimann, C. E. J. Non-Cryst. Solids 1989, 113, 73.
21. Porter, M. D.; Bright, T. B.; Allara, D. L.; Chidsey, C. E. D. J. Am. Chem. Soc. 1987, 109, 3559.
22. Gao, W.; Reven, L. Langmuir 1995, 11, 1860.
23. Kung, K.-H. S.; Hayes, K. F. Langmuir 1993, 9, 263.
24. Vaia, R. A.; Teukolsky, R. K.; Giannelis, E. P. Chem. Mater. 1994, 6, 1017.
25. Delattre, L.; Babonneau, F. Mater. Res. Soc. Symp. Proc. 1994, 346, 365.
26. When the reaction time is extended in these systems, the intensity of the XRD peaks decreases and even disappears in the products reacted for 12 d. The concentration of HCl in the reaction mixture also affected the ordering: the films became amorphous when the molar ratio of HCl to alkoxysilanes was increased to 0.02.
27. Ray, A. Nature 1971, 231, 313.