Heat-induced phase separation of self-assembled monolayers of a fluorocarbon-hydrocarbon asymmetric bisulfide on a Au(111) surface

Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers

Volumn 36, Issue 6 SUPPL. B, 1997, Pages 3909-3912

  Ishida, Takao ^a   Yamamoto, Shin Ichi ^a   Motomatsu, Makoto ^a   Mizutani, Wataru ^b,e   Tokumoto, Hiroshi ^b,e   Hokari, Hirofumi ^c   Azehara, Hiroaki ^c   Fujihira, Masamichi ^c   Kojima, Isao ^d  

^a JT RES CENTER FOR ATOM TECHNOLOGY   (Japan)

^b NATL INST FOR ADV INTERDISC RES   (Japan)

^c TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^d NATL INST OF MAT AND CHEM RES   (Japan)

^e ELECTROTECHNICAL LABORATORY   (Japan)

Author keywords

Dimer; Friction force microscopy (FFM); Gold (Au); Phase separation; Scanning tunneling microscopy (STM); Self assembled monolayer (SAM)

Indexed keywords

EID: 0001667053     PISSN: 00214922     EISSN: None     Source Type: Journal    
DOI: 10.1143/jjap.36.3909     Document Type: Article

References (21)

1. C. E. D. Chidsay, G.-Y. Liu, P. Rowntree and G. Scoles: J. Chem. Phys. 91 (1989) 4421.
2. P. Fenter, A. Eberhardt and P. Eisenberger: Science 266 (1994) 1216.
3. N. Nishida, M. Hara, H. Sasabe and W. Knoll: Jpn. J. Appl. Phys. 35 (1996) 5866.
4. J. B. Schlenoff, M. Li and H. Ly: J. Am. Chem. Soc. 117 (1995) 12528.
5. Ch. Zubrägel, C. Deuper, F. Schneider, M. Neumann, M. Grunze, A. Schertel and Ch. Wöll: Chem. Phys. Lett. 238 (1995) 308.
6. M. S. Yeganeh, S. M. Dougal, R. S. Polizzotti and P. Rabinowitz: Phys. Rev. Lett. 74 (1995) 1811.
7. J. J. Geddy and W. A. Goodard III: J. Am. Chem. Soc. 118 (1996) 3233.
8. E. Delamarche, B. Michel, H. Kang and Ch. Gerber: Langmuir 10 (1994) 4103.
9. T. Ishida, S. I. Yamamoto, W. Mizutani, M. Motomatsu, H. Tokumoto, H. Hokari, H. Azehara and M. Fujihira: to be published in Langmuir 13 (1997).
10. A. Ulman: An Introduction to Ultrathin Organic Films From Langmuir-Blodgett to Self-Assembly (Academic Press, San Diego 1993).
11. H. Schönherr and H. Ringsdorf: Langmuir 12 (1996) 3891.
12. H. Schönherr, H. Ringsdorf, M. Jaschke, H.-J. Butt, E. Bamberg, H. Allinson and S. D. Evans: Langmuir 12 (1996) 3897.
13. S. Y. Dieng, B. Bertaïna and A. Cambon: J. Fluorine Chem. 28 (1985) 341.
14. The fluorocarbon/hydrocarbon phase-separated LB film was investigated by force microscopy and Fujihira et al. concluded that, against our intuition, the fluorocarbon shows larger friction force than the hydrocarbon part; R. M. Overney, E. Meyer, J. Frommer, D. Brodbeck, R. Lüthi, L. Howald, H.-J. Guntherodt, M. Fujihira, H. Takano and Y. Gotoh: Nature 359 (1992) 133.
15. The historical review of the problem of the fluorocarbon/hydrocarbon phase-separated LB film investigated by force microscopy is given; M. Fujihira: Micro/Nanotribology and Its Applications, NATO ASI Series, Series E: Applied Sciences, ed. B. Bhushan Ed. (Kluwer Academic Publishers, Dordrecht, 1997) Vol. 330, p. 239.
16. In the latest report, Takahara et al. also accepted the above conclusion by Fujihira et al.; A. Takahara, K. Kojio, S.-R. Ge and T. Kajiyama: J. Vac. Sci. & Technol. A 14 (1996) 1747.
17. M. Motomatsu, W. Mizutani, H.-Y. Nie and H. Tokumoto: Thin Solid Films 281-282 (1996) 548.
18. K. Ishida, T. Horiuchi, S. Kai and K. Matsushige: Appl. Surf. Sci. 100-101 (1996) 116.
19. M. Walczak, C. Alves, B. Lamp and M. Porter: J. Electroanal. Chem. 396 (1995) 103.
20. D. G. Castner, K. Hinds and D. W. Grainger: Langmuir 12 (1996) 5083.
21. I. Kojima and Y. Saito: private communication.