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Volumn 18, Issue 11, 1999, Pages 2091-2098

1,2-eq,eq-[Re2(CO)8(THF)2]: A reactive Re2(CO)8 fragment that easily activates H-H and C-H bonds

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EID: 0001663536     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9806693     Document Type: Article
Times cited : (28)

References (83)
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    • (1998) 215th National Meeting of the American Chemical Society
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    • Jordan, R.F.1    Guram, A.S.2
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    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1960) Inorg. Synth. , vol.6 , pp. 129
    • Vavoulis, A.1    Austin, T.E.2    Tyree, S.Y.3
  • 9
    • 0001373655 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1962) J. Inorg. Nucl. Chem. , vol.24 , pp. 1105
    • Kern, R.J.1
  • 10
    • 3843095501 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1966) Inorg. Synth. , vol.8 , pp. 49
    • Collman, J.P.1    Kittleman, E.T.2
  • 11
    • 0000451207 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1980) Inorg. Synth. , vol.20 , pp. 119
    • Dilworth, J.R.1    Richards, R.L.2
  • 12
    • 37049092756 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1980) J. Chem. Soc., Dalton Trans. , pp. 2246
    • Davies, J.A.1    Hartley, F.R.2    Murray, S.G.3
  • 13
    • 0000053803 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1982) Inorg. Synth. , vol.21 , pp. 135
    • Manzer, L.E.1
  • 14
    • 0039406640 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1983) Inorg. Chem. , vol.22 , pp. 2642
    • Jones, P.J.1    Hale, A.L.2    Levason, W.3    McCullough, F.P.4
  • 15
    • 0002365708 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1992) Inorg. Synth. , vol.29 , pp. 108
    • Boudjouk, P.1    So, J.-H.2
  • 16
    • 0002039825 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1990) Inorg. Synth. , vol.28 , pp. 33
    • Dilworth, J.R.1    Richards, R.L.2
  • 17
    • 3843049690 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1990) Inorg. Synth. , vol.28 , pp. 36
    • Dilworth, J.R.1    Zubieta, J.2
  • 18
    • 0040999796 scopus 로고
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1990) Inorg. Synth. , vol.28 , pp. 286
    • Deacon, G.B.1    Tuong, T.D.2    Wilkinson, D.L.3
  • 19
    • 0011979869 scopus 로고
    • For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9
    • See for instance: (a) Vavoulis, A.; Austin, T. E.; Tyree, S. Y. Inorg. Synth. 1960, 6, 129. (b) Kern, R. J. J. Inorg. Nucl. Chem. 1962, 24, 1105. (c) Collman, J. P.; Kittleman, E. T. Inorg. Synth. 1966, 8, 49. (d) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1980, 20, 119. (e) Davies, J. A.; Hartley, F. R.; Murray, S. G. J. Chem. Soc., Dalton Trans. 1980, 2246. (f) Manzer, L. E. Inorg. Synth. 1982, 21, 135. (g) Jones, P. J.; Hale, A. L.; Levason, W.; McCullough, F. P. Inorg. Chem. 1983, 22, 2642. (h) Boudjouk, P.; So, J.-H. Inorg. Synth. 1992, 29, 108. (i) Dilworth, J. R.; Richards, R. L. Inorg. Synth. 1990, 28, 33. (j) Dilworth, J. R.; Zubieta, J. Inorg. Synth. 1990, 28, 36. (k) Deacon, G. B.; Tuong, T. D.; Wilkinson, D. L. Inorg. Synth. 1990, 28, 286. (l) Deacon, G. B.; Pain, G. N.; Tuong, T. D. Inorg. Synth. 1990, 28, 291. For a list of crystallographically characterized examples of THF coordination in main-group and transition metals see also the references quoted in ref 9.
    • (1990) Inorg. Synth. , vol.28 , pp. 291
    • Deacon, G.B.1    Pain, G.N.2    Tuong, T.D.3
  • 39
    • 85088809915 scopus 로고    scopus 로고
    • note
    • 2 and suitable organometallic fragments.
  • 54
    • 3843133514 scopus 로고
    • and references therein
    • See for instance: Hansen, P. E. Annu. Rep. NMR Spectrosc. 1983, 15, 104 and references therein.
    • (1983) Annu. Rep. NMR Spectrosc. , vol.15 , pp. 104
    • Hansen, P.E.1
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    • note
    • 15
  • 62
    • 85088809812 scopus 로고    scopus 로고
    • note
    • 3). Attempts to identify the other species have been so far unsuccessful.
  • 70
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    • 2 activation by polynuclear species can be found in: (a) Garland, M.; Pino, P. Organometallics 1990, 9, 1943. (b) Safarowic, F. J.; Bierdeman, D. J.; Keister, J. B. J. Am. Chem. Soc. 1996, 118, 11805.
    • (1990) Organometallics , vol.9 , pp. 1943
    • Garland, M.1    Pino, P.2
  • 71
    • 0029958463 scopus 로고    scopus 로고
    • 2 activation by polynuclear species can be found in: (a) Garland, M.; Pino, P. Organometallics 1990, 9, 1943. (b) Safarowic, F. J.; Bierdeman, D. J.; Keister, J. B. J. Am. Chem. Soc. 1996, 118, 11805.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 11805
    • Safarowic, F.J.1    Bierdeman, D.J.2    Keister, J.B.3
  • 74
    • 85088809696 scopus 로고    scopus 로고
    • note
    • 10].
  • 79
    • 85088810090 scopus 로고    scopus 로고
    • note
    • 8] by reaction with an excess of phenylacetylene, directly into an NMR tube.


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