Kinetics and mechanism of reversible oxidative addition of hydrogen across the metal - metal bond of (μ-H)2Ru3(CO)8(μ-P)(t-Bu)2)2. Steric promotion of metal - metal bond cleavage but a CO dissociative mechanism

Journal of the American Chemical Society

Volumn 118, Issue 47, 1996, Pages 11805-11812

  Safarowic, Fred J ^a   Bierdeman, David J ^a   Keister, Jerome B ^a  

^a UNIVERSITY AT BUFFALO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

METAL COMPLEX;

ARTICLE; DRUG DEGRADATION; REACTION ANALYSIS;

EID: 0029958463     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9628819     Document Type: Article

References (59)

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5. General reviews are given in ref 1. A representative set of significant and leading references for the three-center mechanism is: (a) Chock, P. B.; Halpern. J. J. Am. Chem. Soc. 1966, 88, 3511. (b) Obara, S.; Kitaura, K.; Morokuma, K. J. Am. Chem. Soc. 1984, 106, 7482. (c) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985, 107, 3148. (d) Zhou, P.; Vitale, A. A.; San Filippo. J., Jr.; Saunders, W. H., Jr. J. Am. Chem. Soc. 1985, 107, 8049. (e) Low, J. J.; Goddard, W. A., III Organometallics 1986, 5, 609. (f) Burk, M. J.; McGarth, M. P.; Wheeler, R.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 5034. A general reference concerning molecular hydrogen complexes is: Heinekey, D. M.; Oldham, W. J., Jr. Chem. Rev. 1993, 93, 913.
6. General reviews are given in ref 1. A representative set of significant and leading references for the three-center mechanism is: (a) Chock, P. B.; Halpern. J. J. Am. Chem. Soc. 1966, 88, 3511. (b) Obara, S.; Kitaura, K.; Morokuma, K. J. Am. Chem. Soc. 1984, 106, 7482. (c) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985, 107, 3148. (d) Zhou, P.; Vitale, A. A.; San Filippo. J., Jr.; Saunders, W. H., Jr. J. Am. Chem. Soc. 1985, 107, 8049. (e) Low, J. J.; Goddard, W. A., III Organometallics 1986, 5, 609. (f) Burk, M. J.; McGarth, M. P.; Wheeler, R.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 5034. A general reference concerning molecular hydrogen complexes is: Heinekey, D. M.; Oldham, W. J., Jr. Chem. Rev. 1993, 93, 913.
7. General reviews are given in ref 1. A representative set of significant and leading references for the three-center mechanism is: (a) Chock, P. B.; Halpern. J. J. Am. Chem. Soc. 1966, 88, 3511. (b) Obara, S.; Kitaura, K.; Morokuma, K. J. Am. Chem. Soc. 1984, 106, 7482. (c) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985, 107, 3148. (d) Zhou, P.; Vitale, A. A.; San Filippo. J., Jr.; Saunders, W. H., Jr. J. Am. Chem. Soc. 1985, 107, 8049. (e) Low, J. J.; Goddard, W. A., III Organometallics 1986, 5, 609. (f) Burk, M. J.; McGarth, M. P.; Wheeler, R.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 5034. A general reference concerning molecular hydrogen complexes is: Heinekey, D. M.; Oldham, W. J., Jr. Chem. Rev. 1993, 93, 913.
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