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75
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0038069399
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note
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Actually, a very weak emission around 500 nm was detected for all the species in DMSO and dichloromethane. However, the emission output was at the limit of the sensitivity of our equipment and therefore was not considered.
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78
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0003879317
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VCH: New York
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In principle, an excimer is formed by the combination of a ground-state molecule with an excited-state molecule, a process quite common for aromatic systems (for example, see: Klessinger, M.; Michl, J. Excited States and Photochemistry of Organic Molecules; VCH: New York, 1995). The excimer luminescence is expected to be at longer wavelengths than the monomer luminescence, and the associated emission band is commonly broad and without vibrational structure owing to a transition into the unbound ground state. As an excited-state process, excimer formation also competes with other deactivating processes of the initially formed excited state of the monomer. It should be noted that while this definition fully fits the ππ* luminescence derived from interactions between aromatic moieties (one of them being in its own excited state), the term "excimeric emission" is not formally correct for a MMLCT excited state, for which a metal-metal interaction in the ground state is usually considered. The latter would be more appropriately described as the excited state of a dimeric (or oligomeric) discrete system. However, since in the literature MMLCT emission is very often also called excimeric emission, we decided to use this term in this larger meaning also here, although formal differences should not be forgotten.
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(1995)
Excited States and Photochemistry of Organic Molecules
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Klessinger, M.1
Michl, J.2
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79
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0001642937
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Neve, F.; Crispini, A.; Loiseau, F.; Campagna, S. J. Chem. Soc., Dalton Trans. 2000, 1399.
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(2000)
J. Chem. Soc., Dalton Trans.
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Neve, F.1
Crispini, A.2
Loiseau, F.3
Campagna, S.4
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80
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0038407784
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note
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The influence of higher-energy excited states on the dynamics of emitting states by mixing between the states, with minimal perturbation on the emission energy, is well known. For example, see ref 6.
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81
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Treffert-Ziemelis, S. M.; Golus, J.; Strommen, D.; Kincaid, J. R. Inorg. Chem. 1993, 32, 3890.
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Inorg. Chem.
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Karash, M. S.; Seyler, R. C.; Mayo, F. R. J. Am. Chem. Soc. 1938, 60, 882.
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Karash, M.S.1
Seyler, R.C.2
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