Lewis Acid Promoted [2 + 1] Cycloaddition Reactions of 1-Seleno-2-silylethene with Tricarbonyl-Substituted Olefins

Journal of Organic Chemistry

Volumn 62, Issue 9, 1997, Pages 2968-2974

  Yamazaki, Shoko ^a   Kumagai, Hitoshi ^a   Takada, Takashi ^a   Yamabe, Shinichi ^a   Yamamoto, Kagetoshi ^b  

^a NARA UNIVERSITY OF EDUCATION   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001525655     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9622486     Document Type: Article

References (69)

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61. 2 complexes of 2d; however, the optimized structure and their relative energies gave unreliable results.
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68. 5 On the other hand, the mechanism in Scheme 4 cannot explain the selectivity of three-membered-ring and four-membered-ring formations. A detailed investigation of the intermediacy of Y and Z in this system is now underway. We appreciate the suggestion of the reviewer on the possibility of this alternative mechanism.
69. Cooke, M. P., Jr.; Burman, D. L. J. Org. Chem. 1982, 47, 4955.