Molybdocene Porphyrazines: A Peripheral Dithiolene Metallacycle Fused to a Porphyrinic Core

Inorganic Chemistry

Volumn 37, Issue 9, 1998, Pages 2100-2101

  Goldberg, David P ^a   Michel, Sarah L J ^a   White, Andrew J P ^b   Williams, David J ^b   Barrett, Anthony G M ^b   Hoffman, Brian M ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

^b IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001395213     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971498h     Document Type: Article

References (22)

1. Dailey, K, K.; Yap, G. P. A.; Rheingold. A. L.; Rauchfuss, T. B. Angew. Chem., Int. Ed. Engl. 1996, 35, 1833-1835.
2. Yilmaz, I.; Bekaroǧlu, Ö. Chem. Ber. 1996, 129, 967-971.
3. Crossley, M. I.; Burn, P. L.; Langford, S. J.; Prashar, J. K. J. Chem. Soc., Chem. Commun. 1995, 1921-1923.
4. Baumann, T. F.; Nasir, M. S.; Sibert, J. W.; White, A. J. P.; Olmstead, M. M.; Williams, D. J.; Barrett, A. G. M.; Huffman, B. M. J. Am. Chem. Soc. 1996, 118, 10479-10486.
5. Mani, N. S.; Beall, L. S.; Miller, T.; Anderson, O. P.; Hope, H.; Parkin, S. R.; Williams, D. J.; Barrett, A. G. M.; Hoffman, B. M. J. Chem. Soc., Chem. Commun. 1994, 2095-2096.
6. Cook, A. S.; Williams. D. B. G.; White, A. J. P.; Williams, D. J.; Lange, S. J.; Barrett, A. G. M.; Huffman, B. M. Angew. Chem., Int. Ed. Engl. 1997, 36, 760-761.
7. Schmidt, E. S.; Calderwood, T. S.; Bruice, T. C. lnorg. Chem. 1986, 25, 3718-3720.
8. Miller, J. S.; Vazquez, C.; Calabrese, J. C.; McLean, R. S.; Epstein, A. J. Adv. Mater. 1994, 6, 217-221.
9. Fourmigue, M.; Lenoir, C.; Coulon, C.; Guyon, F.; Amaudrut, J. Inorg. Chem. 1995, 34, 4979-4985.
10. (a) Kajitani, M.; Hagino, G.; Tamada, M.; Fujita, T.; Sakurada, M.; Akiyama, T.; Sugimori, A. J. Am. Chem. Soc. 1996, 118, 489-490.
11. (b) Schrauzer, G. N.; Mayweg, V. P. J. Am. Chem. Soc. 1965, 87, 3585-3592.
12. Jaquinod, L.; Gros, C.; Olmstead, M. M.; Antolovich, M.; Smith. K. M. J. Chem. Soc., Chem. Commun. 1996, 1475-1476.
13. Kobayashi, N. In Phthalocyanines, Properties and Applications; Leznoff, C. C., Lever, A. B. P., Eds.; VCH Publishers Inc.: New York. 1993; Vol. 2, pp 97-161.
14. See Supporting Information for characterization data.
15. Baumann, T. F.; Barrett, A. G. M.; Hoffman, B. M. Inorg. Chem. 1997, 36, 5661-5665.
16. 2 = 0.285 (SHELXTL PC, 5.03).
17. Hsu, J. K.; Bonangelino, C. J.; Kaiwar, S. P.; Boggs, C. M.; Fettinget, J. C.; Pilato, R. S. Inorg. Chem. 1996, 35, 4743-4751.
18. 6 supporting electrolyte, Pt disc working electrode, Ag/AgCl reference electrode, and Ag wire auxiliary electrode. Scan rate 110 mV/s.
19. 2-, -1.77 (102).
20. Lindsell, W. E. J. Chein. Soc., Daltom Trans. 1975, 2548-2552.
21. A conservative estimate of J can be obtained from the partition function for a singlet/triplet system, if we assume that an excited-state signal would be detectable if as few as 10% of the ions were thermally excited to the triplet state.
22. Goldberg, D. P.; Telser, J.; Krzystek, J.; Montalban, A. G.; Brunel., L,-C; Barrett, A. G. M.; Hoffman, B. M. J. Am. Chein. Soc. 1997, 119, 8722-8723.