Intrinsic droplet-size effect on mass transfer rate across a single-microdroplet/water interface: Role of adsorption on a spherical liquid/liquid boundary

Journal of Physical Chemistry B

Volumn 102, Issue 16, 1998, Pages 2908-2913

  Nakatani, Kiyoharu ^a   Sudo, Masumi ^a   Kitamura, Noboru ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001391743     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9730499     Document Type: Article

References (42)

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29. -5 M, although the effective r of the electrode is smaller than 12.5 μm due to contact of a droplet with the electrode. A small shoulder observed at ∼250 mV in the CV (Figure 4) will correspond to oxidation of FeCp-PrOH in the water phase. In the present experiments, the Q(t) value is determined by subtracting the background-current value, so that the contribution of the oxidation current in the water phase to Q(t) is negligibly small.
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