Ozone from iron(III) porphyrin, nitrite ion, and oxygen

Journal of the American Chemical Society

Volumn 118, Issue 16, 1996, Pages 3984-3985

  Castro, Charles E ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

OZONE;

ARTICLE; DRUG MANUFACTURE; REACTION ANALYSIS;

EID: 0029933010     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952028u     Document Type: Article

References (29)

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18. 2 (cf. ref 12).
19. -. Similarly a reaction under oxygen, but without porphyrin, produced no nitrate,
20. (b) All control reactions were run and worked up in a manner identical to that described in the text and consisted of runs (i) with substrate and oxygen, but no porphyrin; (ii) porphyrin, oxygen, and substrate, but no nitrite: (iii) porphyrin, nitnte, and substrate, but no oxygen (reactions under argon). No reaction occurred under any of these conditions. In all cases, only nitrite salt and unreacted olefin were recovered. In particular, neither nitrate, acetone, or acetaldehyde was detected in any control ran.
21. A 2 ft × 1/8 in. Porapak P column at 85 °C/30 mL/min He was employed. Acetone and (2.0 min) tetramethylethylene (2.8-6 min were the only peaks present and corresponded exactly to an authentic standard.
22. -1) and comparison with a standard were 90 ± 10%.
23. 3 (43); for acetaldehyde P (44), P-H (43), and P-CHO (15) were observed.
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