Highly functionalized bicyclo[2.2.2]octenone-fused [60]fullerenes from masked o-benzoquinones and C60

Organic Letters

Volumn 2, Issue 18, 2000, Pages 2909-2912

  Yen, Chi Feng ^a   Peddinti, Rama Krishna ^a   Liao, Chun Chen ^a  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001334284     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol000198s     Document Type: Article

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36. 60 (1 equiv, 50 mg, 0.069 mM) in toluene (1,2-dichlorobenzene for the reactions at 180°C) (10 mL) was stirred at the appropriate temperature over a period of time (Table 1). The solvent was removed under reduced pressure at room temperature [removal of toluene at above room temperature provided monoadducts 3d-h in low yields as a result of (further) formation of bisadducts with unreacted MOBs under high concentrations!], and the residue was purified as in the case of 3a-c to afford pure adducts 3d-h.
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