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85033144630
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note
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2, although formally an 18e complex, is still able to catalyze Heck reaction. See ref 31d.
-
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98
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85033155068
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2, although formally an 18e complex, is still able to catalyze Heck reaction. See ref 31d
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2, although formally an 18e complex, is still able to catalyze Heck reaction. See ref 31d.
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99
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85033134955
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18a,b
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18a,b
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84945431533
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Racemic diphosphines in the biphenyls series were synthesized from aryl iodides by an Ullmann reaction in the presence of a stoechiometric amount of copper(0). See: Schmid, R.; Foricher, J.; Cereghetti, M.; Schönholzer, P. Helv. Chim. Acta 1991, 74, 370.
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For the reduction of phosphine oxide to the corresponding phosphine see: (a) Naumann, K.; Zon, G.; Mislow, K. J. Am. Chem. Soc. 1969, 91, 7012. (b) Uozomi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945.
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For the reduction of phosphine oxide to the corresponding phosphine see: (a) Naumann, K.; Zon, G.; Mislow, K. J. Am. Chem. Soc. 1969, 91, 7012. (b) Uozomi, Y.; Tanahashi, A.; Lee, S.-Y.; Hayashi, T. J. Org. Chem. 1993, 58, 1945.
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85033147023
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Indeed, we observed from Table 6 that using two bidentate phosphine ligands per palladium resulted in either a nonreactive catalyst (entry 7) or a less efficient one (entry 11)
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Indeed, we observed from Table 6 that using two bidentate phosphine ligands per palladium resulted in either a nonreactive catalyst (entry 7) or a less efficient one (entry 11).
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85033137951
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The spectra were compared to those of a commercial sample
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The spectra were compared to those of a commercial sample.
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