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Volumn 15, Issue 24, 1996, Pages 5209-5215

Organoruthenium thermochemistry. Enthalpies of reaction of Cp′Ru(COD)Cl (Cp′ = η5-C5H5 and η5-C5Me5) with tertiary phosphite ligands

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EID: 0001294474     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960319l     Document Type: Article
Times cited : (27)

References (57)
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    • For leading references in this area, see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; J. Wiley and Sons: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds. ACS Symp. Ser. 1990, 428. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics in Organotransition Metal Compounds. Polyhedron Symp. Pr., 1988, 7.
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    • For leading references in this area, see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; J. Wiley and Sons: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503-561. (c) Martinho-Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds. ACS Symp. Ser. 1990, 428. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics in Organotransition Metal Compounds. Polyhedron Symp. Pr., 1988, 7.
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    • See for example: (a) Nolan, S. P.; Hoff, C. D.; Stoutland, P. O.; Newman, L. J.; Buchanan, J. M.; Bergman, R. G.; Yang, G. K.; Peters, K. G. J. Am Chem.Soc. 1987, 109, 3143-3145 and references therein. (b) Nolan, S. P.; Lopez de la Vega, R.; Hoff, C. D. Organometallics, 1986, 5, 2529-2537.
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    • Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, England; Chapter 32.9
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    • Comprehensive Organometallic Chemistry
    • Bennett, M.A.1    Matheson, T.W.2
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    • 0001580672 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1992) Organometallics , vol.11 , pp. 3947-3953
    • Nolan, S.P.1    Martin, K.L.2    Stevens, E.D.3    Fagan, P.J.4
  • 16
    • 0000354660 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1993) Organometallics , vol.12 , pp. 4305-4311
    • Luo, L.1    Fagan, P.J.2    Nolan, S.P.3
  • 17
    • 0001515268 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1994) Organometallics , vol.13 , pp. 669-675
    • Luo, L.1    Zhu, N.2    Zhu, N.-J.3    Stevens, E.D.4    Nolan, S.P.5    Fagan, P.J.6
  • 18
    • 0000151669 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1994) Organometallics , vol.13 , pp. 3621-3627
    • Li, C.1    Cucullu, M.E.2    McIntyre, R.A.3    Stevens, E.D.4    Nolan, S.P.5
  • 19
    • 0000275649 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1994) Organometallics , vol.13 , pp. 4781-4786
    • Luo, L.1    Nolan, S.P.2
  • 20
    • 0000081457 scopus 로고    scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1995) Organometallics , vol.14 , pp. 289-296
    • Cucullu, M.E.1    Luo, L.2    Nolan, S.P.3    Fagan, P.J.4    Jones, N.L.5    Calabrese, J.C.6
  • 21
    • 0000148074 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1995) Organometallics , vol.14 , pp. 1333-1338
    • Luo, L.1    Li, C.2    Cucullu, M.E.3    Nolan, S.P.4
  • 22
    • 0001665189 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1995) Organometallics , vol.14 , pp. 4611-4616
    • Serron, S.A.1    Nolan, S.P.2
  • 23
    • 0001740569 scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1995) Organometallics , vol.14 , pp. 5290-5297
    • Serron, S.A.1    Luo, L.2    Li, C.3    Cucullu, M.E.4    Nolan, S.P.5
  • 24
    • 0000081457 scopus 로고    scopus 로고
    • For organoruthenium systems, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947-3953. (b) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993,12, 4305-4311. (c) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669-675. (d) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621-3627. (e) Luo, L.; Nolan, S. P. Organometallics 1994, 13, 4781-4786. (f) Cucullu, M. E.; Luo, L.; Nolan, S. P.; Fagan, P. J.; Jones, N. L.; Calabrese, J. C. Organometallics 1995, 14, 289-296. (g) Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 1333-1338. (h) Serron, S. A.; Nolan, S. P. Organometallics 1995, 14, 4611-4616. (i) Serron, S. A.; Luo, L.; Li, C.; Cucullu, M. E.; Nolan, S. P. Organometallics 1995, 14, 5290-5297. (j) Li, C.; Serron, S. A.; Nolan, S. P.; Petersen, J. L. Organometallics 1996, 15, 4020-4029.
    • (1996) Organometallics , vol.15 , pp. 4020-4029
    • Li, C.1    Serron, S.A.2    Nolan, S.P.3    Petersen, J.L.4
  • 25
    • 0001540629 scopus 로고
    • For organoiron systems, see: (a) Luo, L.; Nolan, S. P. Organometallics 1992, 11, 3483-3486. (b) Luo, L.; Nolan, S. P. Inorg. Chem. 1993, 32, 2410-2415. (c) Li, C.; Nolan, S. P. Organometallics 1995, 14, 1327-1332. (d) Li, C.; Stevens, E. D.; Nolan, S. P. Organometallics 1995, 14, 3791-3797.
    • (1992) Organometallics , vol.11 , pp. 3483-3486
    • Luo, L.1    Nolan, S.P.2
  • 26
    • 0001156612 scopus 로고
    • For organoiron systems, see: (a) Luo, L.; Nolan, S. P. Organometallics 1992, 11, 3483-3486. (b) Luo, L.; Nolan, S. P. Inorg. Chem. 1993, 32, 2410-2415. (c) Li, C.; Nolan, S. P. Organometallics 1995, 14, 1327-1332. (d) Li, C.; Stevens, E. D.; Nolan, S. P. Organometallics 1995, 14, 3791-3797.
    • (1993) Inorg. Chem. , vol.32 , pp. 2410-2415
    • Luo, L.1    Nolan, S.P.2
  • 27
    • 0001333438 scopus 로고
    • For organoiron systems, see: (a) Luo, L.; Nolan, S. P. Organometallics 1992, 11, 3483-3486. (b) Luo, L.; Nolan, S. P. Inorg. Chem. 1993, 32, 2410-2415. (c) Li, C.; Nolan, S. P. Organometallics 1995, 14, 1327-1332. (d) Li, C.; Stevens, E. D.; Nolan, S. P. Organometallics 1995, 14, 3791-3797.
    • (1995) Organometallics , vol.14 , pp. 1327-1332
    • Li, C.1    Nolan, S.P.2
  • 28
    • 0001221615 scopus 로고
    • For organoiron systems, see: (a) Luo, L.; Nolan, S. P. Organometallics 1992, 11, 3483-3486. (b) Luo, L.; Nolan, S. P. Inorg. Chem. 1993, 32, 2410-2415. (c) Li, C.; Nolan, S. P. Organometallics 1995, 14, 1327-1332. (d) Li, C.; Stevens, E. D.; Nolan, S. P. Organometallics 1995, 14, 3791-3797.
    • (1995) Organometallics , vol.14 , pp. 3791-3797
    • Li, C.1    Stevens, E.D.2    Nolan, S.P.3
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    • note
    • It should be noted here that the difference mentioned is not between absolute bond disruption enthalpies. The Cp vs Cp* effect will also be present in the Ru-COD bond enthalpy.


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