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Volumn 14, Issue 1, 1995, Pages 289-296

Enthalpies of Reaction of (ŋ5-C5H5)Ru(cyclooctadiene)Cl with Tertiary Phosphine Ligands: Ligand Substitution as a Gauge for Metal Basicity and a Linear Correlation of Bond Length and Bond Enthalpy

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EID: 0000081457     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00001a042     Document Type: Article
Times cited : (40)

References (34)
  • 1
    • 0000586619 scopus 로고
    • Bonding Energetics of Organometallic Compounds
    • For leading references in this area, see In Encyclopedia of Inorganic Chemistry; J. Wiley and Sons: New York (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503–561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629–688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds. ACS Symp. Ser. 1990, 428. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics in Organotransition Metal Compounds. Polyhedron Symp. Print 1988, 7. (f) Skinner, H. A.; Connor, J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79–88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41–59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204–238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417–426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1984; pp 43–90. (1) Connor, J. A. Curr. Top. Chem.
    • For leading references in this area, see: (a) Nolan, S. P. Bonding Energetics of Organometallic Compounds. In Encyclopedia of Inorganic Chemistry; J. Wiley and Sons: New York, 1994. (b) Hoff, C. D. Prog. Inorg. Chem. 1992, 40, 503–561. (c) Martinho Simões, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629–688. (d) Marks, T. J., Ed. Bonding Energetics In Organometallic Compounds. ACS Symp. Ser. 1990, 428. (e) Marks, T. J., Ed. Metal-Ligand Bonding Energetics in Organotransition Metal Compounds. Polyhedron Symp. Print 1988, 7. (f) Skinner, H. A.; Connor, J. A. In Molecular Structure and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH: New York, 1987; Vol. 2, Chapter 6. (g) Skinner, H. A.; Connor, J. A. Pure Appl. Chem. 1985, 57, 79–88. (h) Pearson, R. G. Chem. Rev. 1985, 85, 41–59. (i) Mondal, J. U.; Blake, D. M. Coord. Chem. Rev. 1983, 47, 204–238. (j) Mansson, M. Pure Appl. Chem. 1983, 55, 417–426. (k) Pilcher, G.; Skinner, H. A. In The Chemistry of the Metal-Carbon Bond; Harley, F. R., Patai, S., Eds.; Wiley: New York, 1984; pp 43–90. (1) Connor, J. A. Curr. Top. Chem. 1977, 71, 71–110.
    • (1994) , vol.71 , pp. 71-110
    • Nolan, S.P.1
  • 2
    • 33845282616 scopus 로고
    • See, for example and references therein. (b) Nolan, S. P.; Lopez de 1a Vega, R.; Hoff, C. D. Organometallics 1986, 5, 2529–2537
    • See, for example: (a) Nolan, S. P.; Hoff, C. D.; Stoutland, P. O.; Newman, L. J.; Buchanan, J. M.; Bergman, R. G.; Yang, G. K.; Peters, K. G. J. Am. Chem. Soc. 1987, 109, 3143–3145 and references therein. (b) Nolan, S. P.; Lopez de 1a Vega, R.; Hoff, C. D. Organometallics 1986, 5, 2529–2537.
    • (1987) J. Am. Chem. Soc. , vol.109 , pp. 3143-3145
    • Nolan, S.P.1    Hoff, C.D.2    Stoutland, P.O.3    Newman, L.J.4    Buchanan, J.M.5    Bergman, R.G.6    Yang, G.K.7    Peters, K.G.8
  • 3
    • 0011557093 scopus 로고
    • (b) Nolan, S. P.; Stern, D.; Marks, T. J. J. Am. Chem. Soc. 1989, 111, 7844–7854
    • Nolan, S. P.; Porchia, M.; Marks, T. J. Organometallics 1991, 10, 1450–1457. (b) Nolan, S. P.; Stern, D.; Marks, T. J. J. Am. Chem. Soc. 1989, 111, 7844–7854.
    • (1991) Organometallics , vol.10 , pp. 1450-1457
    • Nolan, S.P.1    Porchia, M.2    Marks, T.J.3
  • 4
    • 0345211121 scopus 로고
    • J. In ref 1d, pp 159–174. (b) Nolan, S. P.; Lopez de la Vega, R.; Mukerjee, S. L.; Gonzalez, A. A.; Hoff, C. D. In ref 1e, pp 1491–1498. (c) Marks, T. J.; Gagné, M. R.; Nolan, S. P.; Schock, L. E.; Seyam, A. M.; Stern, D. L. Pure Appl. Chem. 1989, 61, 1665–1672. (d) Schock, L. E.; Marks, T. J.
    • Nolan, S. P.; Stern, D.; Hedden, D.; Marks, T. J. In ref 1d, pp 159–174. (b) Nolan, S. P.; Lopez de la Vega, R.; Mukerjee, S. L.; Gonzalez, A. A.; Hoff, C. D. In ref 1e, pp 1491–1498. (c) Marks, T. J.; Gagné, M. R.; Nolan, S. P.; Schock, L. E.; Seyam, A. M.; Stern, D. L. Pure Appl. Chem. 1989, 61, 1665–1672. (d) Schock, L. E.; Marks, T. J. J. Am. Chem. Soc. 1988, 110, 7701–7715.
    • (1988) J. Am. Chem. Soc. , vol.110 , pp. 7701-7715
    • Nolan, S.P.1    Stern, D.2    Hedden, D.3    Marks, T.4
  • 5
    • 33845279312 scopus 로고
    • (b) Novak, B. M.; Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542–7543. (c) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1992, 114, 3974–3975. (d) Fu, G. C.; Nguyen, S. T.; Grubbs, R. H. J. Am. Chem. Soc. 1993, 115, 9856–9857. (e) Nguyen, S. T.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1993, 115, 9858–9859
    • Novak, B. M.; Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 960–961. (b) Novak, B. M.; Grubbs, R. H. J. Am. Chem. Soc. 1988, 110, 7542–7543. (c) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1992, 114, 3974–3975. (d) Fu, G. C.; Nguyen, S. T.; Grubbs, R. H. J. Am. Chem. Soc. 1993, 115, 9856–9857. (e) Nguyen, S. T.; Grubbs, R. H.; Ziller, J. W. J. Am. Chem. Soc. 1993, 115, 9858–9859.
    • (1988) J. Am. Chem. Soc. , vol.110 , pp. 960-961
    • Novak, B.M.1    Grubbs, R.H.2
  • 7
    • 0001580672 scopus 로고
    • For solution calorimetric investigations of organogroup 8 complexes, see (b) Luo, L.; Nolan, S. P. Organometallics 1992, 11, 3483–3486. (c) Luo, L.; Nolan, S. P. Inorg. Chem. 1993, 32, 2410–2415. (d) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 3405—3411. (e) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669–675. (f) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621—3627
    • For solution calorimetric investigations of organogroup 8 complexes, see: (a) Nolan, S. P.; Martin, K. L.; Stevens, E. D.; Fagan, P. J. Organometallics 1992, 11, 3947–3953. (b) Luo, L.; Nolan, S. P. Organometallics 1992, 11, 3483–3486. (c) Luo, L.; Nolan, S. P. Inorg. Chem. 1993, 32, 2410–2415. (d) Luo, L.; Fagan, P. J.; Nolan, S. P. Organometallics 1993, 12, 3405—3411. (e) Luo, L.; Zhu, N.; Zhu, N.-J.; Stevens, E. D.; Nolan, S. P.; Fagan, P. J. Organometallics 1994, 13, 669–675. (f) Li, C.; Cucullu, M. E.; McIntyre, R. A.; Stevens, E. D.; Nolan, S. P. Organometallics 1994, 13, 3621—3627.
    • (1992) J. Organometallics , vol.11 , pp. 3947-3953
    • Nolan, S.P.1    Martin, K.L.2    Stevens, E.D.3    Fagan, P.4
  • 8
    • 0003102650 scopus 로고
    • (b) Bryndza, H. E.; Fong, L. K.; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456. (c) Collman, J. P.; McElwee-White, L.; Brothers, P. J.; Rose, E. J. Am. Chem. Soc. 1986, 108, 1332–1333
    • mancuso, C.; Halpern, J. J. Organomet. Chem. 1992, 428, C8-C11. (b) Bryndza, H. E.; Fong, L. K.; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456. (c) Collman, J. P.; McElwee-White, L.; Brothers, P. J.; Rose, E. J. Am. Chem. Soc. 1986, 108, 1332–1333.
    • (1992) J. Organomet. Chem. , vol.428 , pp. C8-C11
    • mancuso, C.1    Halpern, J.2
  • 9
    • 33845197246 scopus 로고
    • 2+
    • (b) Wishart, J. F.; Taube, H.; Breslauer, K. L.; Isied, S. S. Inorg. Chem. 1984, 23, 2997–3001
    • 2+; see, for example: (a) Wishart, J. F.; Taube, H.; Breslauer, K. L.; Isied, S. S. Inorg. Chem. 1986, 25, 1479–1481. (b) Wishart, J. F.; Taube, H.; Breslauer, K. L.; Isied, S. S. Inorg. Chem. 1984, 23, 2997–3001.
    • (1986) Inorg. Chem. , vol.25 , pp. 1479-1481
    • Wishart, J.F.1    Taube, H.2    Breslauer, K.L.3    Isied, S.S.4
  • 10
    • 0000149561 scopus 로고
    • (b) Nolan, S. P.; Lopez de la Vega, R.; Hoff, C. D. Inorg. Chem. 1986, 25, 4446–4448
    • Nolan, S. P.; Hoff, C. D.; landrum, J. T. J. Organomet. Chem. 1985, 282, 357–362. (b) Nolan, S. P.; Lopez de la Vega, R.; Hoff, C. D. Inorg. Chem. 1986, 25, 4446–4448.
    • (1985) J. Organomet. Chem. , vol.282 , pp. 357-362
    • Nolan, S.P.1    Hoff, C.D.2    landrum, J.T.3
  • 11
    • 0000531681 scopus 로고
    • (b) Rottink, M. K.; Angelici, R. J. J. Am. Chem. Soc. 1993, 115, 7267–7274
    • Sowa, J. R., Jr.; Angelici, R. J. J. Am. Chem. Soc. 1991, 113, 2537–2544. (b) Rottink, M. K.; Angelici, R. J. J. Am. Chem. Soc. 1993, 115, 7267–7274.
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 2537-2544
    • Sowa, J.R.1    Angelici, R.J.2
  • 13
    • 0003487210 scopus 로고    scopus 로고
    • Principles and Applications of Organotransition Metal Chemistry
    • 2nd ed.; University Science: Mill Valley, CA, 1987. (b) Bennett, M. A.; Matheson, T. W. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, England, 1982; Chapter 32.9. (c) Mitsudo, T.; Naruse, H.; Kondo, T.; Ozaki, Y.; Watanabe, Y. Angew. Chem., Int. Ed. Engl. 1994, 33, 580–581
    • Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry, 2nd ed.; University Science: Mill Valley, CA, 1987. (b) Bennett, M. A.; Matheson, T. W. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, England, 1982; Chapter 32.9. (c) Mitsudo, T.; Naruse, H.; Kondo, T.; Ozaki, Y.; Watanabe, Y. Angew. Chem., Int. Ed. Engl. 1994, 33, 580–581.
    • Collman, J.P.1    Hegedus, L.S.2    Norton, J.R.3    Finke, R.G.4
  • 14
    • 0004055425 scopus 로고
    • Purification of Laboratory Chemicals
    • 3rd ed.; Pergamon Press: New York, NY
    • Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals, 3rd ed.; Pergamon Press: New York, NY, 1988.
    • (1988)
    • Perrin, D.D.1    Armarego, W.L.F.2
  • 19
    • 0007569988 scopus 로고
    • (b) Bruce, M. I.; Wong, F. S.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1981, 1398–1405. (c) Bruce, M. I.; Wong, F. S.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1982, 2203–2207
    • Treichel, P. M.; Komar, D. A. Synth. React. Inorg. Met.-Org. Chem. 1980, 10, 205–210. (b) Bruce, M. I.; Wong, F. S.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1981, 1398–1405. (c) Bruce, M. I.; Wong, F. S.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1982, 2203–2207.
    • (1980) Synth. React. Inorg. Met.-Org. Chem. , vol.10 , pp. 205-210
    • Treichel, P.M.1    Komar, D.A.2
  • 20
    • 0010997167 scopus 로고
    • (b) Bruce, M. I.; Cifuentes, M. P.; Snow, M. R.; Tiekink, R. T. J. Organomet. Chem. 1989, 359, 379–399.
    • Treichel, P. M.; Komar, D. A. Synth. React. Inorg. Met.-Org. Chem. 1984, 14, 383–400. (b) Bruce, M. I.; Cifuentes, M. P.; Snow, M. R.; Tiekink, R. T. J. Organomet. Chem. 1989, 359, 379–399.
    • (1984) Synth. React. Inorg. Met.-Org. Chem. , vol.14 , pp. 383-400
    • Treichel, P.M.1    Komar, D.A.2
  • 23
    • 0000260821 scopus 로고
    • For reviews, see (b) Baker R. Chem. Rev. 1973, 73, 487–530. (c) Hegedus, L. S. J. Organomet. Chem. Libr. 1976, 1, 329–359. (d) Billington, D. C. Chem. Soc. Rev. 1985, 14, 93–120
    • For reviews, see: (a) Semmelhack, M. F. Org. React. 1972, 19, 115–198. (b) Baker R. Chem. Rev. 1973, 73, 487–530. (c) Hegedus, L. S. J. Organomet. Chem. Libr. 1976, 1, 329–359. (d) Billington, D. C. Chem. Soc. Rev. 1985, 14, 93–120.
    • (1972) Org. React. , vol.19 , pp. 115-198
    • Semmelhack, M.F.1
  • 24
    • 1542639278 scopus 로고
    • (b) Noyori, R.; Takaya, H. Acc. Chem. Res. 1990, 23, 345–350. (c) Inoue, S.-I.; Takaya, H.; Tani, K.; Otsuka, S.; Sato, T.; Noyori, R. J. Am. Chem. Soc. 1990, 112, 4897–4905. (d) Otsuka, S.; Tani, K. Synthesis 1991, 665–680. (e) Yamakawa, M.; Noyori, R. Organometallics 1992, 11, 3167—3169 and references therein
    • Noyori, R. Science 1990, 248, 1194–1199. (b) Noyori, R.; Takaya, H. Acc. Chem. Res. 1990, 23, 345–350. (c) Inoue, S.-I.; Takaya, H.; Tani, K.; Otsuka, S.; Sato, T.; Noyori, R. J. Am. Chem. Soc. 1990, 112, 4897–4905. (d) Otsuka, S.; Tani, K. Synthesis 1991, 665–680. (e) Yamakawa, M.; Noyori, R. Organometallics 1992, 11, 3167—3169 and references therein.
    • (1990) Science , vol.248 , pp. 1194-1199
    • Noyori, R.1
  • 28
    • 0003601187 scopus 로고
    • Homogeneous Catalysis with Metal Phosphine Complexes
    • Plenum: New York
    • Pignolet, L. H., Ed. Homogeneous Catalysis with Metal Phosphine Complexes; Plenum: New York, 1983.
    • (1983)
    • Pignolet, L.H.1
  • 29
    • 11644311048 scopus 로고
    • (b) Manzer, L. E.; Tolman, C. A. J. Am. Chem. Soc. 1975, 97, 1955–1986
    • Tolman, C. A. Chem. Rev. 1977, 77, 313—348. (b) Manzer, L. E.; Tolman, C. A. J. Am. Chem. Soc. 1975, 97, 1955–1986.
    • (1977) Chem. Rev. , vol.77 , pp. 313-348
    • Tolman, C.A.1
  • 30
    • 33751552810 scopus 로고
    • (b) Fernandez, A. L.; Prock, A.; Geiring, W. P. Organometallics 1994, 13, 2767—2772
    • Liu, H.-Y.; Eriks, K.; Geiring, W. P. Organometallics 1990, 9, 1758–1766. (b) Fernandez, A. L.; Prock, A.; Geiring, W. P. Organometallics 1994, 13, 2767—2772.
    • (1990) Organometallics , vol.9 , pp. 1758-1766
    • Liu, H.-Y.1    Eriks, K.2    Geiring, W.P.3
  • 33
    • 0000759794 scopus 로고
    • (b) Trost has also recently reported the catalytic use of 1 in a butenolide synthesis: Trost, B. M.; Müller, T. J. J. J. Am. Chem. Soc. 1994, 116, 4985–4986
    • Trost, B. M.; Martinez, J. A.; Kulawiec, R. J.; Indolese, A. F. J. Am. Chem. Soc. 1993, 115, 10402–10403. (b) Trost has also recently reported the catalytic use of 1 in a butenolide synthesis: Trost, B. M.; Müller, T. J. J. J. Am. Chem. Soc. 1994, 116, 4985–4986.
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 10402-10403
    • Trost, B.M.1    Martinez, J.A.2    Kulawiec, R.J.3    Indolese, A.F.4
  • 34
    • 0011453920 scopus 로고
    • For recent observation of such isomerization and oligomerization by a ruthenium complex
    • For recent observation of such isomerization and oligomerization by a ruthenium complex, see: Carreno, R.; Chaudret, B.; Labroue, D.; Sabo-Etienne, S. Organometallics 1993, 12, 13–14.
    • (1993) Organometallics , vol.12 , pp. 13-14
    • Carreno, R.1    Chaudret, B.2    Labroue, D.3    Sabo-Etienne, S.4


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