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0347498897
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For the investigations on diastereoselective ring cleavage reactions described here, it was sufficient to prepare the complex 5b in a racemic form.
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0346237918
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note
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The relative configuration at the biaryl axis was determined by NOE/ROE experiments, showing a correlation between the hydroxy proton and the methyl group protons of the Cp* ligand.
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0347498898
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note
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The use of the older Gaussian 92 program package, by contrast, showed only large values of the Fukui function in the region of the metal center and the Michael acceptor and phenylogous Michael acceptor positions.
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