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Volumn 21, Issue 8, 1997, Pages 919-927

Ligand effect on the insertion of SnCl2 in dichloroplatinum(II) complexes of symmetrical and mixed amino(do)phosphine-phosphinite chelates. X-ray crystal structure of PtCl2{(S)-Ph,Cy-ProNOP}

Author keywords

Aminophosphine phosphinite ligands; Insertion; Platinum tin complexes

Indexed keywords


EID: 0001233098     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (15)

References (50)
  • 36
    • 31044447141 scopus 로고    scopus 로고
    • note
    • 1H experiments (couplings ∼10 Hz). As a typical example, for complex 2b, the phosphorus resonance at δ 77.6 ppm showed two correlations with δ 3.45-3.7 ppm (2m, 2 x 1H, OCHH) and 8.0 ppm (2 m, 2 x 2H, o-H aro), and was thus assigned to P(O); the resonance at δ 74.2 ppm showed correlations with δ 1.2-2.3 ppm (m, CH Cy and 1H, CHHN), 2.65 ppm (m, 1H, CHHN), and 4.55 ppm (m, 1H, NCH), which was consistent for the P(N) signal.
  • 38
    • 31044438920 scopus 로고    scopus 로고
    • note
    • It is noteworthy that in the course of Rh(I)/AMPP-catalyzed hydrogenation of prochiral ketones, both catalytic activity and enantioselectivity are controlled by the aminophosphine moiety. See refs 7b, d.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.