Monophospholyl analogs of cobaltocenium, rhodocenium, and iridocenium cations. Molecular structures of [MCp*(η5-PC4H2tBu2)] +BPh4- (M = Co, Rh)

Organometallics

Volumn 19, Issue 6, 2000, Pages 954-956

  Forissier, Kareen ^a   Ricard, Louis ^a   Carmichael, Duncan ^a   Mathey, François ^a  

^a LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001225491     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990820o     Document Type: Article

References (28)

1. (a) Carmichael, D.; Ricard, L.; Mathey, F. J. Chem. Soc., Chem. Commun. 1994, 1167.
2. (b) Carmichael, D.; Ricard, L.; Mathey, F. J. Chem. Soc., Chem. Commun. 1994, 2459.
3. (c) Caffyn, A. J. M.; Carmichael, D.; Mathey, F.; Ricard, L. Organometallics 1997, 16, 2049.
4. (a) Forissier, K.; Ricard, L.; Carmichael, D.; Mathey, F. Chem. Commun. 1999, 1273.
5. (b) Schnepf, A.; Stösser, G.; Carmichael, D.; Mathey, F.; Schnöckel, H. Angew. Chem., Int. Ed. 1999, 38, 1646.
6. Nief, F.; Mathey, F. J. Chem. Soc., Chem. Commun. 1988, 770.
7. +; 100%).
8. For example: Mathey, F.; Mitschler, A.; Weiss, R. J. Am. Chem. Soc. 1978, 100, 5748.
9. Mathey, F. Coord. Chem. Rev. 1994, 37, 1.
10. -3. All data were collected on a KappaCCD diffractometer at 150.0(1) K using Mo Kα radiation (λ = 0.710 73 Å). Full details are given in the Supporting Information.
11. Schleyer, P. v. R.; Freeman, P. K.; Jiao, H.; Goldfuss, B. Angew. Chem., Int. Ed. Engl. 1995, 34, 337.
12. +: Dixon, D. A.; Miller, J. S. J. Am. Chem. Soc. 1987, 109, 3656.
13. Gloaguen, B.; Astruc, D. J. Am. Chem. Soc. 1990, 112, 4607.
14. (a) Lemoine, P.; Gross, M.; Braunstein, P.; Mathey, F.; Deschamps, B.; Nelson, J. H. Organometallics 1984, 3, 1303,
15. (b) Lemoine, P.; Gross, M.; Braunstein, P.; Mathey, F.; Deschamps, B.; Nelson, J. H. J. Organomet. Chem. 1985, 295, 189. Roman, E.; Leiva, A. M.; Casasempere, M. A.; Charrier, C.; Mathey, F.; Garland, M. T.; Le Marouille, J. Y. J. Organomet. Chem. 1986, 309, 323.
16. (b) Lemoine, P.; Gross, M.; Braunstein, P.; Mathey, F.; Deschamps, B.; Nelson, J. H. J. Organomet. Chem. 1985, 295, 189. Roman, E.; Leiva, A. M.; Casasempere, M. A.; Charrier, C.; Mathey, F.; Garland, M. T.; Le Marouille, J. Y. J. Organomet. Chem. 1986, 309, 323.
17. (d) Bartsch, R.; Datsenko, S.; Ignatiev, N. V.; Müller, C.; Nixon, J. F.; Pickett, C. J. J. Organomet. Chem. 1997, 529, 375.
18. (e) Weber, L.; Sommer, O.; Stammler, H.-G.; Neumann, B.; Kölle, U. Chem. Ber. 1995, 128, 665.
19. (f) For further electrochemistry of phospholyl complexes, see also: Feher, R.; Kohler, F. H.; Nief, F.; Ricard, L.; Rossmayer, S. Organometallics 1997, 16, 4610 and references therein.
20. (a) Envers, A.; Heinemann, F.; Kummer, S.; Wrackmeyer, B.; Zenneck, U. Lecture LF3-3 to XIVth ICPC, Cincinnati, OH, July 12-17, 1998.
21. After Submission, two fuller descriptions have appeared: (b) Envers, A.; Heinemann, F.; Wrackmeyer, B.; Zenneck, U. Chem. Eur. J. 1999, 5, 3143. (c) Envers, A.; Heinemann, F.; Kummer, S.; Wrackmeyer, B.; Zeller, M.; Zenneck, U. Phosphorus, Sulfur Silicon Relat. Elem. 1999, 144-6, 725.
22. After Submission, two fuller descriptions have appeared: (b) Envers, A.; Heinemann, F.; Wrackmeyer, B.; Zenneck, U. Chem. Eur. J. 1999, 5, 3143. (c) Envers, A.; Heinemann, F.; Kummer, S.; Wrackmeyer, B.; Zeller, M.; Zenneck, U. Phosphorus, Sulfur Silicon Relat. Elem. 1999, 144-6, 725.
23. (a) An undetected hexaphosphacobaltocene was suggested as a conceivable intermediate in the synthesis of a triphospholyl(triphosphadiene)cobalt(I) compound: Bartsch, R.; Hitchcock, P. B.; Nixon, J. F. J. Chem. Soc., Chem. Commun. 1988, 819.
24. (b) Other reactions of triphospholides with Co and Rh(III) precursors have given complex redox products: Nixon, J. F. Coord. Chem. Rev. 1995, 145, 201.
25. (c) Cobalt triple-decker monophospholyl compounds: Chase, K. J.; Bryan, R. F.; Woods, M. K.; Grimes, R. N. Organometallics 1991, 10, 2631.
26. (d) Diazacobaltocenium: Kuhn, N.; Köckerling, M.; Stubenrauch, S.; Bläser, D.; Boese, R. J. Chem. Soc., Chem. Commun. 1988, 819.
27. See also: (e) Kuhn, N.; Köckerling, M.; Stubenrauch, S.; Bläser, D.; Boese, R. Z. Naturforsch., B 1999, 54B, 424. (f) Borole analogues of cobaltocenium salts: Herberich, G. E. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A.; Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 1, p 197.
28. See also: (e) Kuhn, N.; Köckerling, M.; Stubenrauch, S.; Bläser, D.; Boese, R. Z. Naturforsch., B 1999, 54B, 424. (f) Borole analogues of cobaltocenium salts: Herberich, G. E. In Comprehensive Organometallic Chemistry II; Wilkinson, G., Stone, F. G. A.; Abel, E. W., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 1, p 197.