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[21] using geometries optimized at the RI-DFT level. 2: E = -2730.201229 au, Ga-P 266.2, Ga-C 256.7 and 253.4, P-C 179, C-C 138.1, C-C 142.2 pm, C-P-C 90.9, P-C-C 110.4, C-C-C 114.1 . 5: E = -4346.064324 au, Ga-P 249.9, Ga-C 246.3 and 242.1, Ga-Cr 241.4, P-C 184.9, C-C 138.7, C-C 143.4 pm, C-P-C 88.9 , P-C-C 110.9°, C-C-C 114.6.
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Comparison between the Ga-C and Ga-P distances of the calculated phospholylgallium(I) and the chromium pentacarbonyl adduct show the same trends. The Ga-P length decreases by 16 pm, whilst Ga-C decreases by 11 pm.
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[10] involves the reduction of the corresponding phospholylgallium dihalide with potassium. Further synthetic investigations and preliminary CVD experiments aimed at the formation of GaP are in progress.
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