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Volumn 38, Issue 11, 1999, Pages 1646-1649

η5-Phospholylgallium: The first monomeric polyhapto compound between a phospholyl ligand and a main group metal

Author keywords

Ab inition calculations; Gallium; P ligands; Phospholes

Indexed keywords

ALKALI METAL; GALLIUM; LIGAND; MONOMER; PHOSPHORUS; PHOSPHORUS DERIVATIVE;

EID: 0345711473     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990601)38:11<1646::AID-ANIE1646>3.0.CO;2-Z     Document Type: Article
Times cited : (32)

References (29)
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    • note
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    • note
    • [21] using geometries optimized at the RI-DFT level. 2: E = -2730.201229 au, Ga-P 266.2, Ga-C 256.7 and 253.4, P-C 179, C-C 138.1, C-C 142.2 pm, C-P-C 90.9, P-C-C 110.4, C-C-C 114.1 . 5: E = -4346.064324 au, Ga-P 249.9, Ga-C 246.3 and 242.1, Ga-Cr 241.4, P-C 184.9, C-C 138.7, C-C 143.4 pm, C-P-C 88.9 , P-C-C 110.9°, C-C-C 114.6.
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    • note
    • Comparison between the Ga-C and Ga-P distances of the calculated phospholylgallium(I) and the chromium pentacarbonyl adduct show the same trends. The Ga-P length decreases by 16 pm, whilst Ga-C decreases by 11 pm.
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    • note
    • [10] involves the reduction of the corresponding phospholylgallium dihalide with potassium. Further synthetic investigations and preliminary CVD experiments aimed at the formation of GaP are in progress.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.