Existence of negative activation energies in simple bimolecular metathesis reactions and some observations on too-fast reactions

Journal of Physical Chemistry A

Volumn 102, Issue 27, 1998, Pages 5175-5181

  Benson, Sidney W ^a   Dobis, Otto ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001221788     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp972873u     Document Type: Article

References (58)

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50. el = 2. This lowers the A-factor by a factor of 2, making it a factor of 4 lower than the experimentally observed A-factor. This is poor agreement, which also suggests that the TS is bent rather than linear (see e.g.: Aoiz, F. J.; Banares, L.; Martinez-Haya, B.; Castillo, J. F.; Manolopoulos, D. E.; Stark, K.; Werner, H.-J. J. Phys. Chem. A 1997, 101, 6403, and Stark, K.; Werner, H.-J. J. Chem. Phys. 1996, 104, 6515, and references therein).
51. el = 2. This lowers the A-factor by a factor of 2, making it a factor of 4 lower than the experimentally observed A-factor. This is poor agreement, which also suggests that the TS is bent rather than linear (see e.g.: Aoiz, F. J.; Banares, L.; Martinez-Haya, B.; Castillo, J. F.; Manolopoulos, D. E.; Stark, K.; Werner, H.-J. J. Phys. Chem. A 1997, 101, 6403, and Stark, K.; Werner, H.-J. J. Chem. Phys. 1996, 104, 6515, and references therein).
52. el = 2. This lowers the A-factor by a factor of 2, making it a factor of 4 lower than the experimentally observed A-factor. This is poor agreement, which also suggests that the TS is bent rather than linear (see e.g.: Aoiz, F. J.; Banares, L.; Martinez-Haya, B.; Castillo, J. F.; Manolopoulos, D. E.; Stark, K.; Werner, H.-J. J. Phys. Chem. A 1997, 101, 6403, and Stark, K.; Werner, H.-J. J. Chem. Phys. 1996, 104, 6515, and references therein).
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