Temperature coefficients of rates of ethyl radical reactions with HBr and Br in the 228-368 K temperature range at millitorr pressures

Journal of Physical Chemistry A

Volumn 101, Issue 34, 1997, Pages 6030-6042

  Dobis, Otto ^a   Benson, Sidney W ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; BINDING ENERGY; BROMINE; BROMINE COMPOUNDS; DISSOCIATION; ENTHALPY; HALOGENATION; MATHEMATICAL MODELS; REACTION KINETICS; THERMAL EFFECTS;

BROMINATION;

FREE RADICAL REACTIONS;

EID: 0031212143     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970822r     Document Type: Article

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54. It is difficult to present kinetic data in graphic form that covers more than 2 decades in k without making experimental errors appear very small. Reduced Arrhenius plots overcome this problem. We believe that this is the first use of such plots.