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Volumn 62, Issue 20, 1997, Pages 6961-6967

Anionic Additions to Glycosyl Iodides: Highly Stereoselective Syntheses of β C-, N-, and O-Glycosides

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EID: 0001117517     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo970922t     Document Type: Article
Times cited : (90)

References (29)
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    • and references cited therein
    • Hodosi, G.; Kovác, P. J. Am. Chem. Soc. 1997, 119, 2335. Crich, D.; Sun, S. J. Org. Chem. 1996, 61, 4506 and references cited therein.
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    • note
    • In the course of these experiments we observed that after complete conversion of the iodide the acetate began to reappear on TLC, suggesting that a nucleophilic acetate species was displacing the iodide. This problem was alleviated by removing trimethylsilyl acetate from the reaction by azeotrope with toluene.


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