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Volumn 11, Issue 7, 1999, Pages 1776-1783

Coordination networks of C3v and C2v phenylacetylene nitriles and silver(I) salts: Interplay of ligand symmetry and molecular dipole moments in the solid state

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EID: 0001104107     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm981153c     Document Type: Article
Times cited : (48)

References (91)
  • 2
    • 0000407885 scopus 로고
    • Crystal engineering of novel materials composed of infinite two-and three-dimensional frameworks
    • Bein, T., Ed.; ACS Symposium Series 499; American Chemical Society: Washington, DC; Chapter 19
    • (b) Robson, R.; Abrahams, B. F.; Batten, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. Crystal Engineering of Novel Materials Composed of Infinite Two-and Three-Dimensional Frameworks. In Supramolecular architecture: synthetic control in thin films; Bein, T., Ed.; ACS Symposium Series 499; American Chemical Society: Washington, DC, 1992; Chapter 19; p 256.
    • (1992) Supramolecular Architecture: Synthetic Control in Thin Films , pp. 256
    • Robson, R.1    Abrahams, B.F.2    Batten, S.R.3    Gable, R.W.4    Hoskins, B.F.5    Liu, J.6
  • 6
    • 0007770222 scopus 로고
    • A multitopic ligand is one equipped with multiple coordination site and, due to a rigid geometry, is unable to chelate to a metal center. See the examples of Ag(I) or Cu(I) coordination networks based on tetratopic ligands and some other extended structures. (a) Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546.
    • (1990) J. Am. Chem. Soc. , vol.112 , pp. 1546
    • Hoskins, B.F.1    Robson, R.2
  • 43
    • 80051477719 scopus 로고    scopus 로고
  • 52
    • 0001568341 scopus 로고    scopus 로고
    • (a) For the synthetic procedures of 4-ethenylbenzonitrile, see: (a) Hirsch, K. A.; Wilson, R. W.; Moore, J. S. Inorg. Chem. 1997, 36, 2960. Also, for examples of the preparation of phenylacetylenes via palladium-catalyzed cross coupling reactions, see
    • (1997) Inorg. Chem. , vol.36 , pp. 2960
    • Hirsch, K.A.1    Wilson, R.W.2    Moore, J.S.3
  • 56
    • 0001568341 scopus 로고    scopus 로고
    • 2c-d,3a,c,4t,11b A table of known organic silver triflate complexes is included in the Supporting Information. The triflate counterion always enters the coordination sphere of silver(I) if the crystallization solvent is an aromatic solvent such as benzene or toluene. Such "capping" effectively reduces the coordination number of silver(I) available for nitrogen-containing ligands to a maximum of three and inhibit it from forming the four-connected network. If the coordination number of the metal ion is four and the constituent ligand is tritopic, the (4, 3) net is also possible as can be seen in ref 3d (b) Hirsch, K. A.; Wilson, R. W.; Moore, J. S. Inorg. Chem. 1997, 36, 2960.
    • (1997) Inorg. Chem. , vol.36 , pp. 2960
    • Hirsch, K.A.1    Wilson, R.W.2    Moore, J.S.3
  • 57
    • 80051476104 scopus 로고    scopus 로고
    • For the examples of bridging triflate ion in the silver(I) complexes, see refs 9, 11b, and 11d
    • (c) For the examples of bridging triflate ion in the silver(I) complexes, see refs 9, 11b, and 11d.
  • 69
    • 0001438097 scopus 로고
    • Chemla, D. S., Zyss, J., Eds.; Academic Press: New York
    • The permanent dipole moment is an important factor leading to noncentrosymmetry in organic crystals. See: (a) Nicoud, J. F.; Twieg, R. J. In Non-Linear Optical Properties of Organic Molecules and Crystals; Chemla, D. S., Zyss, J., Eds.; Academic Press: New York, 1987; Vol. 1; p 253.
    • (1987) Non-Linear Optical Properties of Organic Molecules and Crystals , vol.1 , pp. 253
    • Nicoud, J.F.1    Twieg, R.J.2
  • 72
    • 0003732720 scopus 로고
    • 4th ed.; Clarendon Press: Oxford, U.K.
    • (b) Wells, A. F. Structura Inorganic Chemistry, 4th ed.; Clarendon Press: Oxford, U.K., 1975; p 102.
    • (1975) Structura Inorganic Chemistry , pp. 102
    • Wells, A.F.1
  • 88
    • 0004232548 scopus 로고
    • Springer: Berlin
    • (k) Reference 4t. (17) The interface of double-diamond may be compared with a mathematical model for tetrahedral minimal surface by Schultz. See: Schwarz, H. A. Gesammelte Mathematische Abhandlung; Springer: Berlin, 1890; Vol 1
    • (1890) Gesammelte Mathematische Abhandlung , vol.1
    • Schwarz, H.A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.